Handrin A. Ibrahim
Editorial Notes
NOTICE OF CONCERN: ACM has received evidence that casts doubt on the integrity of the peer review process for the DATA 2019 Conference. As a result, ACM is issuing a Notice of Concern for all papers published and strongly suggests that the papers from this Conference not be cited in the literature until ACM's investigation has concluded and final decisions have been made regarding the integrity of the peer review process for this Conference.
ABSTRACT
The effects of central metal ion Zn(II), Ni (II)) at single-decker on spectral properties of pure hexadeca fluorinated phthalocyanine (F16Pc) in the gas phase were performed. Theoretical (UV-Vis, electronic structures, IR spectroscopy and optical properties), by density functional theory calculations (DFT) were studied. Ultraviolet- Visible (UV-vis) spectra revealed a narrow energy band gap for all complex, were coincided to presence of fluorine atoms. The F16Pc and its derivatives exhibited the followings order of energy gap NiF16P > ZnF16P > F16Pc.The frontier orbitals and electrostatic potential surface are not significantly changed by an addition the central metal atom. Apart of these, we performed an elaborate assignment for all intensely bands in vibrational spectra of metal-free hexadecafluorinated phthalocyanine and 3d-metal fluorinated phthalocyanines.
- F. Rückerl, D. Waas, B. Büchner, M. Knupfer, Particular electronic properties of F16CoPc: A decent electron acceptor material, J. Electron Spectros. Relat. Phenomena. 215 (2017) 1--7. Google Scholar
Cross Ref
- S. Şahin, S. Altun, A. Altindal, Z. Odabaş, Synthesis of novel azo-bridged phthalocyanines and their toluene vapour sensing properties, Sensors Actuators, B Chem. 206 (2015) 601--608. Google ScholarCross Ref
- M. Grobosch, C. Schmidt, R. Kraus, M. Knupfer, Electronic properties of transition metal phthalocyanines: The impact of the central metal atom (d5-d10), Org. Electron. Physics, Mater. Appl. 11 (2010) 1483--1488. Google ScholarCross Ref
- M.A. Abood, A.F. Abdulameer, I.M. Ai-essa, F.I. Mustafa, Optical Investigations of Bulk Heterojunction Blend (NiPcTs / PEDOT : PSS) Thin Films, 2 (2016) 6--11.Google Scholar
- H. Ahn, W.-H. Liou, H.-M.P. Chen, C.-H. Hsu, Anisotropic exciton relaxation in nanostructured metal (Zn and F16Zn)-phthalocyanine, Opt. Express. 23 (2015) 3230--3235. Google ScholarCross Ref
- M.S. Fakir, Z. Ahmad, K. Sulaiman, Modification of optical band gap and surface morphology of NiTsPc thin films, Chinese Phys. Lett. 29 (2012). Google ScholarCross Ref
- M. Neghabi, M. Zadsar, S.M.B. Ghorashi, Investigation of structural and optoelectronic properties of annealed nickel phthalocyanine thin films, Mater. Sci. Semicond. Process. 17 (2014) 13--20. Google ScholarCross Ref
- N. Li, W. Lu, K. Pei, Y. Yao, W. Chen, Ordered-mesoporous-carbon-bonded cobalt phthalocyanine: A bioinspired catalytic system for controllable hydrogen peroxide activation, ACS Appl. Mater. Interfaces. 6 (2014) 5869--5876. Google ScholarCross Ref
- E.A. Lukyanets, V.N. Nemykin, The key role of peripheral substituents in the chemistry of phthalocyanines and their analogs, J. Porphyr. Phthalocyanines. 14 (2010) 1--40. Google ScholarCross Ref
- F. Petraki, H. Peisert, J. Uihlein, U. Aygül, T. Chassé, CoPc and CoPcF16 on gold: Site-specific charge-transfer processes, Beilstein J. Nanotechnol. 5 (2014) 524--531. Google ScholarCross Ref
- M.E. Azim-Araghi, S. Riyazi, Synthesis, morphology and optical properties of nanocomposite thin films based on polypyrrole-bromo-aluminium phthalocyanine, J. Mater. Sci. Mater. Electron. 24 (2013) 4488--4493. Google ScholarCross Ref
- K.J. Hamam, M.I. Alomari, A study of the optical band gap of zinc phthalocyanine nanoparticles using UV-Vis spectroscopy and DFT function, Appl. Nanosci. 7 (2017) 261--268. Google ScholarCross Ref
- B. Keskin, O. Okuyucu, A. Altindal, A. Erdoǧmuş, Novel indium(iii) phthalocyanines; Synthesis, photophysical and humidity sensing properties, New J. Chem. 40 (2016) 5537--5545. Google ScholarCross Ref
- K. Cnops, G. Zango, J. Genoe, P. Heremans, M.V. Martinez-Diaz, T. Torres, D. Cheyns, Energy Level Tuning of Non-Fullerene Acceptors in Organic Solar Cells, J. Am. Chem. Soc. 137 (2015) 8991--8997. Google ScholarCross Ref
- Ö.T. Özmen, K. Goksen, A. Demir, M. Durmuş, O. Köysal, Investigation of photoinduced change of dielectric and electrical properties of indium (III) phthalocyanine and fullerene doped nematic liquid crystal, Synth. Met. 162 (2012) 2188--2192. Google ScholarCross Ref
- D. Arican, A. Erdoǧmuş, A. Koca, Electrochromism of the Langmuir-Blodgett films based on monophthalocyanines carrying redox active metal centers, Thin Solid Films. 550 (2014) 669--676. Google ScholarCross Ref
- K. Ishii, Functional singlet oxygen generators based on phthalocyanines, Coord. Chem. Rev. 256 (2012) 1556--1568. Google ScholarCross Ref
- J.T. Ping, H.S. Peng, W.B. Duan, F.T. You, M. Song, Y.Q. Wang, Synthesis and optimization of ZnPc-loaded biocompatible nanoparticles for efficient photodynamic therapy, J. Mater. Chem. B. 4 (2016) 4482--4489. Google ScholarCross Ref
- C.A.Z. Souto, K.P. Madeira, D. Rettori, M.O. Baratti, L.B.A. Rangel, D. Razzo, A.R. Da Silva, Improved photodynamic action of nanoparticles loaded with indium (III) phthalocyanine on MCF-7 breast cancer cells, J. Nanoparticle Res. 15 (2013). Google ScholarCross Ref
- M. Managa, M.A. Idowu, E. Antunes, T. Nyokong, Photophysicochemical behavior and antimicrobial activity of dihydroxosilicon tris(diaquaplatinum)octacarboxyphthalocyanine, Spectrochim. Acta - Part A Mol. Biomol. Spectrosc. 125 (2014) 147--153. Google ScholarCross Ref
- J. Weissbecker, A. Loas, S.M. Gorun, D. Schlettwein, Switching of the Rate-limiting Step in the Electrochromic Reduction of Fluorinated Phthalocyanine Thin Films by Decreased Intermolecular Coupling, Electrochim. Acta. 157 (2015) 232--244. Google ScholarCross Ref
- C. Wang, H. Dong, W. Hu, Y. Liu, D. Zhu, Semiconducting π-Conjugated Systems in Field-Effect Transistors, Chem. Rev. 112 (2012) 2208--2267. Google ScholarCross Ref
- M.J. Jurow, B.A. Hageman, E. DiMasi, C.-Y. Nam, C. Pabon, C.T. Black, C.M. Drain, Controlling morphology and molecular packing of alkane substituted phthalocyanine blend bulk heterojunction solar cells, J. Mater. Chem. A. 1 (2013) 1557--1565. Google ScholarCross Ref
- M. Jurow, A. Varotto, V. Manichev, N.A. Travlou, D.A. Giannakoudakis, C.M. Drain, Self-organized nanostructured materials of alkylated phthalocyanines and underivatized C60 on ITO, RSC Adv. 3 (2013) 21360--21364. Google ScholarCross Ref
- S.K. Das, A. Mahler, A.K. Wilson, F. D'Souza, High-potential perfluorinated phthalocyanine-fullerene dyads for generation of high-energy charge-separated states: Formation and photoinduced electron-transfer studies, ChemPhysChem. 15 (2014) 2462--2472. Google ScholarCross Ref
- G.S.S. Saini, S.D. Dogra, K. Sharma, S. Singh, S.K. Tripathi, V. Sathe, R.K. Singh, Experimental and density functional theoretical study of the effects of chemical vapours on the vibrational spectra of nickel phthalocyanine thin films, Vib. Spectrosc. 57 (2011) 61--71. Google ScholarCross Ref
- M.J.. et al. Frisch, Official Gaussian 09 Literature Citation, Gaussian 09, Revis. D.01; Gaussian Inc. Wallingford CT J. (2009).Google Scholar
- A. Suzuki, T. Oku, Effects of central metal on electronic structure, magnetic properties, infrared and Raman spectra of double-decker phthalocyanine, Appl. Surf. Sci. 380 (2016) 127--134. Google ScholarCross Ref
- S.D. Dogra, S. Singh, S. Kaur, S.K. Tripathi, G.S.S. Saini, Effect of pyridine on zinc phthalocyanine studied by density functional theory calculations and infrared absorption spectroscopy, Vib. Spectrosc. 56 (2011) 60--65. Google ScholarCross Ref
- H. Jiang, J. Ye, P. Hu, F. Wei, K. Du, N. Wang, T. Ba, S. Feng, C. Kloc, Fluorination of metal phthalocyanines: Single-crystal growth, efficient N-channel organic field-effect transistors, and structure-property relationships, Sci. Rep. 4 (2014) 1--6. Google ScholarCross Ref
- T. V. Basova, N.S. Mikhaleva, A.K. Hassan, V.G. Kiselev, Thin films of fluorinated 3d-metal phthalocyanines as chemical sensors of ammonia: An optical spectroscopy study, Sensors Actuators, B Chem. 227 (2016) 634--642. Google ScholarCross Ref
- R. Ridhi, S. Singh, G.S.S. Saini, S.K. Tripathi, Comparison of interaction mechanisms of copper phthalocyanine and nickel phthalocyanine thin films with chemical vapours, J. Phys. Chem. Solids. 115 (2018) 119--126. Google ScholarCross Ref
- S. Heutz, G. Rumbles, T.S. Jones, Thin film properties and surface morphology of metal free phthalocyanine films grown by organic molecular beam deposition, Phys Chem Chem Phys. (1999) 1--4. http://pubs.rsc.org/en/content/articlepdf/1999/cp/a904089g%5Cnpapers2://publication/uuid/21C87196-F218-4584-BF8A-EEF535401767.Google Scholar
- G.S.S. Saini, S. Singh, S. Kaur, R. Kumar, V. Sathe, S.K. Tripathi, Zinc phthalocyanine thin film and chemical analyte interaction studies by density functional theory and vibrational techniques, J. Phys. Condens. Matter. 21 (2009). Google ScholarCross Ref
- N. Prabavathi, A. Nilufer, V. Krishnakumar, Vibrational spectroscopic (FT-iR and FT-Raman) studies, natural bon orbital analysis and molecular electrostatic potential surface of isoxanthopterin, Spectrochim. Acta - Part A Mol. Biomol. Spectrosc. 114 (2013) 101--113. Google ScholarCross Ref
- E.J. Braga, B.T. Corpe, M.M. Marinho, E.S. Marinho, Molecular electrostatic potential surface, HOMO-LUMO, and computational analysis of synthetic drug Rilpivirine, Int. J. Sci. Eng. Res. 7 (2016) 315--319.Google Scholar
- D. V. Konarev, S.I. Troyanov, A. V. Kuzmin, Y. Nakano, M. Ishikawa, M.A. Faraonov, S.S. Khasanov, A.L. Litvinov, A. Otsuka, H. Yamochi, G. Saito, R.N. Lyubovskaya, The Salts of Copper Octafluoro- and Hexadecafluorophthalocyanines Containing [CuII(F8Pc)4-]2-Dianions and [CuF16Pc]-Monoanions, Inorg. Chem. 56 (2017) 1804--1813. Google ScholarCross Ref
Recommendations
The UV and blue light emission properties of Mn doped ZnO nanocrystals
We present a study of the light emission properties over wavelengths from UV to blue of Mn doped ZnO nanocrystals fabricated by means of a thermal evaporation vapor phase deposition process. The samples were grown with a Mn mole ratio in the Zn/Mn mixed ...
Investigation of electronic structure, optical properties, map of electrostatic potential, and toxicity of HfO2, Hf0.88Si0.12O2, Hf0.88Ge0.12O2 and Hf0.88Sn0.12O2 by computational and virtual screening
AbstractThis research work presents a computational investigation of hafnium(IV) oxide and its crystals doped by Si, Ge and Sn atoms, replacing the oxygen atom in HfO2. Hafnium(IV) oxide, which has a wide band gap, has been used in power electronics ...
Structural and optical properties of BST thin films prepared by the sol-gel process
The Ba0.65Sr0.35TiO3 thin films have been prepared by the sol-gel method on fused quartz and (1102)- oriented Al2O3 substrates. The crystallization behavior and structure characterization were studied at different annealing temperatures by XRD and SEM. ...
Comments