Visible Absorption Properties of Retinoic Acid Controlled on Hydrogenated Amorphous Silicon Thin Film

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Published 15 February 2008 Copyright (c) 2008 The Japan Society of Applied Physics
, , Citation Yutaka Tsujiuchi et al 2008 Jpn. J. Appl. Phys. 47 1211 DOI 10.1143/JJAP.47.1211

1347-4065/47/2S/1211

Abstract

Langmuir–Blodgett (LB) films of retinoic acid and LB films of retinoic acid mixed with a peptide that contains an alanine–lysine–valine (AKV) amino acid sequence deposited on a hydrogenated amorphous silicon (a-Si:H) film prepared by electron cyclotron resonance (ECR) plasma sputtering were fabricated, and their light absorption spectrums were compared. A specific visible light absorption at approximately 500 nm occurred in a film that had a film thickness of more than 80 nm and a hydrogen concentration of more than 20% in the sputtering process gas. Mixing the AKV sequence peptide with retinoic acid caused a 6 nm blueshift, from 363 to 357 nm, of the absorption maximum of the composite LB film on a SiO2 substrate. Using the same peptide, a large 30 nm blueshift, from 500 to 470 nm, was induced in the composite LB film on the a-Si:H film.

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10.1143/JJAP.47.1211