Phonon Raman Spectroscopy in Bi2Sr2Ca1-xYxCu2O8+y

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Copyright (c) 1989 The Japan Society of Applied Physics
, , Citation Shunji Sugai and Masatoshi Sato 1989 Jpn. J. Appl. Phys. 28 L1361 DOI 10.1143/JJAP.28.L1361

1347-4065/28/8A/L1361

Abstract

The hole concentration dependence of the lattice vibrations in Bi2Sr2Ca1-xYxCu2O8+y was investigated by Raman spectroscopy. A full assignment of the vibrational modes in CuO5 pyramidal layers was made. The anisotropy between x and y is large for the phonon energies. On decreasing the hole concentration, the energy shifts of the vibrational modes of layered O atoms are larger than those of apical O atoms, which indicates that doped holes enter the layered O sites. The resonant enhancement of the Ag modes at 141 and 187 cm-1 and the B1g mode at 326 cm-1 indicates strong electronphonon interactions.

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10.1143/JJAP.28.L1361