Polarization and Dipole Moments of Manganese-Modified Potassium Sodium Strontium Barium Niobate Crystals

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Copyright (c) 1997 The Japan Society of Applied Physics
, , Citation H. R. Xia et al 1997 Jpn. J. Appl. Phys. 36 2179 DOI 10.1143/JJAP.36.2179

1347-4065/36/4R/2179

Abstract

The crystal growth, the ferroelectric hysteresis loops, and the infrared reflectivity spectra of manganese-modified potassium sodium strontium barium niobate (KNSBN) single crystals are reported. Compared with the undoped KNSBN crystals, the manganese-modified crystals have stable hysteresis loops, whose spontaneous polarization is about 0.18 C/m2 and coercive field strength is about 600 V/mm, but those of the undoped KNSBN crystals are about 0.04 C/m2 and 530 V/mm, respectivery. The experimental results of the infrared reflectivity spectra show that the infrared reflectivities vary as the orientations of the dipole moments. The c-axis becomes the stablest orientation of the dipole moments owing to the manganese doping, and the polarization will be locked and not recede if the manganese-modified crystals are polarized into mono-domain.

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10.1143/JJAP.36.2179