Oxide-Phase Simulated Thermodynamics and Calculation of Thermochemical Properties of Compounds Auxiliary to Y–Ba–Cu–O High Tc Superconductors*

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Copyright (c) 1994 The Japan Society of Applied Physics
, , Citation Jaroslav Šesták et al 1994 Jpn. J. Appl. Phys. 33 97 DOI 10.1143/JJAP.33.97

1347-4065/33/1R/97

Abstract

Evaluation methods for the estimation of standard enthalpy and entropy of formation, the temperature dependence of heat capacity and the temperature and heat of melting are shown for a generalised description of oxides. The calculation is applied to an actual simulation of the thermochemical data of real and hypothetical compounds for the following Y:Ba:Cu ratios: 123, 112, 213, 235, 133, 223, 135, 247, 124, 125, 516, 145, 146, 415, 132, 153, 312, 385, 163, 232, 143, 212, 122, 211, 121, 152, 131, 221, 321 and 142.

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10.1143/JJAP.33.97