Abstract
A predictable numerical relationship describing the electrical/mechanical behavior of the carbon nanotube (CNT)-based nanocomposite laminates can realize dynamic health monitoring for the composite components to provide vital information of service status. This paper outlined the parameter-based numerical equations by analyzing the electrical conduction mechanism of the CNT Bucky paper sensor from both the micro- and macro-levels. The CNT-based nanosensors cut from Bucky paper with 500 mg CNT concentration were selected to explore the electrical/mechanical responses relationships during the different flexural strain stages (50%, 80%, and 100% fraction of the fracture strain). Subsequently, the desirable agreement between the experimental curve and the fitting curve obtained from a new series of CNT-based composite specimens demonstrated the validity, suitability, and flexibility of this fitting curve. Finally, the sensors with the reasonable CNT content, film thickness, and dense conductive networks have been selected as suitable sensors for monitoring the mechanical behavior of the composite laminates, which offered the adequate bonding of the fiber–resin–CNT interface to provide higher piezoresistive sensitivity and stable resistance changing process.
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Data Availability Statement
This manuscript has associated data in a data repository. [Authors’ comment: The data sets supporting the results of this article are included within the article.]
References
M. Norkhairunnisa, A. Azizan, M. Mariatti, H. Ismail, L. Sim, Thermal stability and electrical behavior of polydimethylsiloxane nanocomposites with carbon nanotubes and carbon black fillers. J. Compos. Mater. 46(8), 903–910 (2012)
S. Laflamme, A. Downey, F. Ubertini, A. D'Alessandro, AL Materazzi, Novel nanocomposite clay brick for strain sensing in structural masonry. IEEE International Conference on Environment & Electrical Engineering & IEEE Industrial & Commercial Power Systems Europe IEEE (2017)
J.J. Ku-Herrera, F. Avilés, Cyclic tension and compression piezoresistivity of carbon nanotube/ vinyl ester composites in the elastic and plastic regimes. Carbon 50(7), 2592–2598 (2012)
Y.F. Zhu, L. Zhou, Q.S. Jiang, One-dimensional ZnO nanowires grown on three-dimensional scaffolds for improved photocatalytic activity. Ceram. Int. 46(1), 1158 (2019)
H. Aguilar-Bolados, M. Yazdani-Pedram, A. Contreras-Cid, M.A. Lopez-Manchado, A. May-Pat, F. Aviles, Influence of the morphology of carbon nanostructures on thepiezoresistivity of hybrid natural rubber nanocomposites. Compos. B Eng. 109, 147–154 (2017)
L. Guadagno, M. Raimondo, L. Vertuccio, M. Mauro, G. Guerra, K. Lafdi et al., Optimization of graphene-based materials outperforming host epoxy matrices. RSC Adv. 5(46), 36969–36978 (2015)
S. Wu, R.B. Ladani, J. Zhang, K. Ghorbani, X. Zhang, A.P. Mouritz et al., Strain sensors with adjustable sensitivity by tailoring the microstructure of graphene aerogel/PDMS nanocomposites. ACS Appl. Mater. Interfaces 8, 24853–24861 (2016)
A. Sanli, A. Benchirouf, C. Müller, O. Kanoun, Piezoresistive performance characterization of strain sensitive multi-walled carbon nanotube-epoxy nanocomposites. Sens. Actuators A Phys 254, 61–68 (2017)
L. Shen, L. Liu, W. Wang, Y. Zhou, In situ self-sensing of delamination initiation and growth in multi-directional laminates using carbon nanotube interleaves. Compos. Sci. Technol. 167, 141–147 (2018)
M.Y. Chao, Y.G. Wang, D. Ma, X.X. Wu, W.X. Zhang, L.Q. Zhang et al., Wearable MXene nanocomposites-based strain sensor with tile-like stacked hierarchical microstructure for broad-range ultrasensitive sensing. ACS Appl. Mater Interfaces 78, 105187–105196 (2020)
H. Chu, Z. Zhang, Y. Liu, J. Leng, Self-heating fiber reinforced polymer composite using meso/macropore carbon nanotube paper and its application in deicing. Carbon 66, 154–163 (2014)
Q. Song, F. Ye, X. Yin, W. Li, B. Wei, Carbon nanotube–multilayered graphene edge plane core-shell hybrid foams for ultrahigh-performance electromagnetic-interference shielding. Adv. Mater. 29(31), 1701583 (2017)
B. Wang, Y. Duan, Z. Xin, X. Yao, D. Abliz, G. Ziegmann, Fabrication of an enriched graphene surface protection of carbon fiber/epoxy composites for lightning strike via a percolating-assisted resin film infusion method. Compos. Sci. Technol. 158, 51–60 (2018)
R. Zhang, P.F. Pan, Q. Dai, X. Yang, Z. Yang, J. Wei et al., Sensitive and wearable carbon nanotubes/ carbon black strain sensors with wide linear ranges for human motion monitoring. J. Mater. Sci. Mater. Electron. 29(7), 5589–5596 (2018)
H. Songjia, L. Chunrui, X. Huihua, Y. Dongyuan, Y. Kanghong, Z. Huanliang et al., Multiscale nanowire-microfluidic hybrid strain sensors with high sensitivity and stretchability. Npj Flex. Electron. 2(1), 16 (2018)
Y. He, D. Wu, M. Zhou, Y. Zheng, T.F. Wang, C. Lu et al., Wearable strain sensors based on a porous polydimethylsiloxane hybrid with carbon nanotubes and graphene. ACS Appl. Mater. Interfaces 13(13), 15572–15583 (2021)
Z.X. Jia, Z.J. Li, S.F. Ma, W.Q. Zhang, Y.J. Chen, Y.F. Luo et al., Constructing conductive titanium carbide nanosheet (MXene) network on polyurethane/polyacrylonitrile fibre framework for flexible strain sensor. J. Colloid. Interf. Sci. 584(12), 1–10 (2021)
X. Wang, H. Sun, X. Yue, Y. Yu, G. Zheng, K. Dai et al., A highly stretchable carbon nanotubes/ thermoplastic polyurethane fiber-shaped strain sensor with porous structure for human motion monitoring. Compos. Sci. Technol. 168(10), 126–132 (2018)
G. Yin, N. Hu, Y. Karube, Y. Liu, Y. Li, H. Fukunaga, A carbon nanotube/polymer strain sensor with linear and anti-symmetric piezoresistivity. J. Compos. Mater. 11(12), 10691–10723 (2011)
Y. Zheng, Y. Li, K. Dai, M. Liu, K. Zhou, G. Zheng et al., Conductive thermoplastic polyurethane composites with tunable piezoresistivity by modulating the filler dimensionality for flexible strain sensors. Compos. Part A Appl. Sci. Manuf. 101, 41–49 (2017)
N.T. Selvan, S.B. Eshwaran, A. Das, K.W. Stöckelhuber, S. Wießner, P. Pötschke et al., Piezoresistive natural rubber-multiwall carbon nanotube nanocomposite for sensor applications. Sens. Actuators A Phys. 239, 102–113 (2016)
G. Yang, L. Liu, Z. Wu, Improved strain sensing capability of nano-carbon free-standing buckypapers based strain gauges. Smart Mater. Struct. 28(6), 065009 (2019)
J. Wen, Z. Xia, F. Choy, Damage detection of carbon fiber reinforced polymer composites via electrical resistance measurement. Compos. B Eng. 42(1), 77–86 (2011)
C. Zhao, Z.D. Xia, X.L. Wang, J.K. Nie, H. Pei, S.F. Zhao, 3D-printed highly stable flexible strain sensor based on silver-coated-glass fiber-filled conductive silicon rubber. Mater. Design 193, 108788–108798 (2020)
E.F.R.D. Costa, A.A. Skordos, I.K. Partridge, A. Rezai, RTM processing and electrical performance of carbon nanotube modified epoxy/fibre composites. Compos. Part A Appl. Sci. Manuf. 43(4), 593–602 (2012)
C.L. Han, G.D. Wang, N. Li, M. Wang, X.L. Liu, J.H. MA, Study on interlaminar performance of CNTs/epoxy film enhanced GFRP under low-temperature cycle. Compos. Struct. 272(7), 114191–114202 (2021)
G.D. Wang, N. Li, S.K. Melly, T. Peng, Y.C. Li, Q.D. Zhao et al., Monitoring the drilling process of GFRP laminates with carbon nanotube buckypaper sensor. Compos. Struct. 208, 114–126 (2019)
I. Gaztelumendi, M. Chapartegui, R. Seddon, F. Sonia, F. Pons, J. Cinquin, Enhancement of electrical conductivity of composite structures by integration of carbon nanotubes via bulk resin and/or buckypaper films. Compos. B Eng. 122, 31–40 (2017)
L. Liu, J.W. Wu, Y.X. Zhou, Enhanced delamination initiation stress and monitoring sensitivity of quasi-isotropic laminates under in-plane tension by interleaving with CNT buckypaper. Compos. Part A Appl. Sci. Manuf. 89, 10–17 (2016)
L.F. Ma, W. Yang, Y.S. Wang, H. Chen, Y.F. Xing, J.C. Wang et al., Multi-dimensional strain sensor based on carbon nanotube film with aligned conductive networks. Compos. Sci. Technol. 165, 190–197 (2018)
D. Lee, H.P. Hong, C.J. Lee, C.W. Park, N.K. Min, Microfabrication and characterization of spray-coated single-wall carbon nanotube film strain gauges. Nanotechnology 22(45), 455301 (2011)
Y. Lu, M.C. Biswas, Z.H. Guo, J.-W. Jeon, E.K. Wujcik, Recent developments in bio-monitoring via advanced polymer nanocomposite-based wearable strain sensors. Biosens. Bioelectron. 123, 167–177 (2019)
L. Vertuccio, L. Guadagno, G. Spinelli, P. Lamberti, V. Tucci, S. Russo, Piezoresistive properties of resin reinforced with carbon nanotubes for health-monitoring of aircraft primary structures. Compos. B Eng. 107, 192–202 (2016)
F. Panozzo, M. Zappalorto, M. Quaresimin, Analytical model for the prediction of the piezoresistive behavior of CNT modified polymers. Compos. B Eng. 109, 53–63 (2017)
Y. Kuronuma, T. Takeda, Y. Shindo, F. Narita, Z. Wei, Electrical resistance-based strain sensing in carbon nanotube/polymer composites under tension: analytical modeling and experiments. Compos. Sci. Technol. 72(14), 1678–1682 (2012)
J.G. Simmons, Generalized formula for the electric tunnel effect between similar electrodes separated by a thin insulating film. J. Appl. Phys. 34(6), 1793–1803 (1963)
G.R. Ruschau, S. Yoshikawa, R.E. Newnham, Resistivities of conductive composites. J. Appl. Phys. 72(3), 953–959 (1992)
T. Takeda, Y. Shindo, Y. Kuronuma, F. Narita, Modeling and characterization of the electrical conductivity of carbon nanotube-based polymer composites. Polym 52(17), 3852–3856 (2011)
G. Spinelli, P. Lamberti, V. Tucci, V. Luigi, G. Liberata, Experimental and theoretical study on piezoresistive properties of a structural resin reinforced with carbon nanotubes for strain sensing and damage monitoring. Compos. B Eng. 145, 90–99 (2018)
N.D. Alexopoulos, C. Bartholome, P. Poulin, Z. Marioli-Riga, Structural health monitoring of glass fiber reinforced composites using embedded carbon nanotube (CNT) fibers. Compos. Sci. Technol. 70(2), 260–271 (2010)
J.M. Gere, B.J. Goodno. Mechanics of materials. 8th edition. Stanford University (2012)
M. Amjadi, K.U. Kyung, I. Park, M. Sitti, Stretchable, skin-mountable, and wearable strain sensors and their potential applications: a review. Adv. Funct. Mater. 26(11), 1678–1698 (2016)
G. Shi, Z. Zhao, J.H. Pai, I. Lee, L. Zhang, C. Stevenson et al., Highly sensitive, wearable, durable strain sensors and stretchable conductors using graphene/silicon rubber composites. Adv. Funct. Mater. 26(42), 7614–7625 (2016)
C. Bonavolontà, C. Camerlingo, G. Carotenuto, S.D. Nicola, A. Longo, C. Meola et al., Characterization of piezoresistive properties of graphene-supported polymer coating for strain sensor applications. Sens. Actuators A Phys. 252, 26–34 (2016)
M. Wang, B. Li, G.D. Wang, Q.D. Zhao, X.L. Liu, High-sensitive flexural sensors for health monitoring of composite materials using embedded carbon nanotube (CNT) buckypaper. Compos Struct 261, 113280 (2020)
Acknowledgements
The authors would like to thank the Shenyang Aerospace University and Liaoning Key Laboratory of Advanced Polymer Matrix Composites Manufacturing Technology for supporting the materials, equipment, and other research activities.
Funding
This work was supported by Special Zone of National Defense Science and Technology Innovation: 18-H863-31-ZD-002–001-20 and Foundation of Liaoning Province Education Administration No. JYT2020013.
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CLH was involved in writing—original draft preparation, software, data curation, writing—original draft preparation, writing—review and editing, validation, investigation; ALZ contributed to methodology, supervision; G-DW was involved in conceptualization, methodology; NL contributed to conceptualization, supervision; MW, LW and XLL were involved in Validation.
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Han, C.L., Zou, A.L., Wang, GD. et al. The synergetic relation of flexural strain behaviors and electrical signals of carbon nanotube-based polymer laminates. Eur. Phys. J. Plus 137, 462 (2022). https://doi.org/10.1140/epjp/s13360-022-02641-7
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DOI: https://doi.org/10.1140/epjp/s13360-022-02641-7