Abstract.
We report on a systematic study of the implantation of size-selected Ag N + clusters on a graphite sample, for different cluster sizes (N = 1,3,7,9,13) and different impact energies (E = 1-30 keV). Results show that the implantation depth scales linearly with the momentum of the cluster, with a stopping power which depends on cluster size. We have particularly investigated the effects of the size and the geometry of the cluster on the implantation into the graphite substrate. A sort of universal behavior, which unifies different elements and different cluster geometries, can be recognized by scaling the momentum with the cluster projected surface. The stopping power of the cluster while penetrating the HOPG surface has been investigated for each cluster size, and a “molecular effect” is recognized, meaning that the stopping power is not additive in the number of atoms of the cluster.
Similar content being viewed by others
References
U. Heiz, W.D. Schneider, J. Phys. D: Appl. Phys. 33, R85 (2000)
U. Heiz, W.D. Schneider, Crit. Rev. Sol. St. Mat. Sci. 26, 251 (2001)
R. Schaub, H. Jödicke, F. Brunet, R. Monot, J. Buttet, W. Harbich, Phys. Rev. Lett. 86, 3590 (2001)
D.J. Kenny, S. Weller, M. Couillard, R.E. Palmer, C.F. Sanz-Navarro, R. Smith, Eur. Phys. J. D 16, 115 (2001)
S.J. Carroll, S.G. Hall, R.E. Palmer, R. Smith, Phys. Rev. Lett. 81, 3715 (1998)
S.J. Carroll, K. Seeger, R.E. Palmer, Appl. Phys. Lett. 72, 305 (1998)
S.J. Carroll, P. Weibel, B.v. Issendorff, L. Kuipers, R.E. Palmer, J. Phys.: Condens. Matter 8, L617 (1996)
S.J. Carroll, P.D. Nellist, R.E. Palmer, S. Hobday, R. Smith, Phys. Rev. Lett. 84, 2654 (2000)
S.J. Carroll, R.E. Palmer, P.A. Mulheran, S. Hobday, R. Smith, Appl. Phys. A 67, 613 (1998)
S.J. Carroll, S. Pratontep, M. Streun, R.E. Palmer, S. Hobday, R. Smith, J. Chem. Phys. 113, 7723 (2000)
I.M. Goldby, L. Kuipers, B.v. Issendorff, R.E. Palmer, Appl. Phys. Lett. 69, 2819 (1996)
C.M. Grimaud, R.E. Palmer, J. Phys.: Condens. Matter 13, 1869 (2001)
J.R. Hahn, H. Kang, Surf. Sci. 446, L77 (2000)
S.G. Hall, M.B. Nielsen, R.E. Palmer, J. Appl. Phys. 83, 733 (1998)
B. Kaiser, T.M. Bernhardt, K. Rademann, Appl. Phys. A 66, S711 (1998)
D.J. Kenny, R.E. Palmer, C.F. Sanz-Navarro, R. Smith, J. Phys.: Condens. Matter 14, 185 (2002)
S. Pratontep, P. Preece, C. Xirouchaki, R.E. Palmer, C.F. Sanz-Navarro, D.J. Kenny, R. Smith, Phys. Rev. Lett. 90, 055503 (2003)
C.T. Reimann, S. Andersson, P. Bruhwiler, N. Martensson, L. Olsson, R. Erlandosson, M. Henkel, H.M. Urbassek, Nucl. Instrum. Meth. Phys. Res. B 140, 159 (1998)
C.F. Sanz-Navarro, R. Smith, D.J. Kenny, S. Pratontep, R.E. Palmer, Phys. Rev. B 65, 1 (2002)
W. Yamaguchi, K. Yoshimura, Y. Tai, Y. Maruyama, K. Igarashi, S. Tanemura, J. Murakami, J. Chem. Phys. 112, 9961 (2000)
G. Bräuchle, S.R. Schneider, D. Illig, J. Rockenberger, R.D. Beck, M.M. Kappes, Appl. Phys. Lett. 67, 52 (1995)
G. Bräuchle, S.R. Schneider, D. Illig, R.D. Beck, H. Schreiber, M.M. Kappes, Nucl. Instrum. Meth. Phys. Res. B 112, 105 (1996)
J.R. Hahn, H. Kang, Surf. Sci. 357-358, 165 (1996)
S.M. Lee, Y.H. Lee, Y.G. Hwang, J.R. Hahn, H. Kang, Phys. Rev. Lett. 82, 217 (1999)
D. Marton, H. Bu, K.J. Boyd, S.S. Todorov, A.H. Al-Bayati, J.W. Rabalais, Surf. Sci. 326, L489 (1995)
C.T. Reimann, P.A. Sullivan, A. Turpitz, S. Altmann, A.P. Quist, A. Bergman, S.O. Oscarsson, B.U.R. Sundqvist, P. Hakansson, Surf. Sci. 341, L1019 (1995)
Y.-J. Zhu, T.A. Hansen, S. Ammerman, J.D. McBride, T.P. Beebe, J. Phys. Chem. B 105, 7632 (2001)
G. Vandoni, C. Félix, R. Monot, J. Buttet, W. Harbich, Chem. Phys. Lett. 229, 51 (1994)
H. Chang, A.J. Bard, J. Am. Chem. Soc. 113, 5588 (1991)
X. Chu, L.D. Schmidt, Carbon 29, 1251 (1991)
F. Stevens, L.A. Kolodny, T.P. Beebe, J. Phys. Chem. B 102, 10799 (1998)
S.H. Pan, International Patent Publication Number WO 93/19494 (international Bureau, World Intellectual Property Organization, 1993)
S.H. Pan, E.W. Hudson, J. Davis, Rev. Sci. Instrum. 70, 1459 (1999)
R. Coratger, A. Claverie, A. Chahboun, V. Landry, F. Ajustron, J. Beauvillain, Surf. Sci. 262, 208 (1992)
T. Li, B.V. King, R.J. MacDonald, G.F. Cotterill, D.J. O’Connor, Q. Yang, Surf. Sci. 312, 399 (1994)
S. Gilb, M. Blom, G. Bräuchle, C. Stoermer, R. Wellmann, M.M. Kappes (not published)
J.R. Hahn, H. Kang, J. Vacuum Sci. Technol. A 17, 1606 (1999)
V.I. Shulga, P. Sigmund, Nucl. Instrum. Meth. Phys. Res. B 47, 236 (1990)
V.I. Shulga, Nucl. Instrum. Meth. Phys. Res. B 58, 422 (1991)
Z. Pan, Nucl. Instrum. Meth. Phys. Res. B 66, 325 (1992)
V. Bonacić-Koutecky, L. Cespiva, P. Fantucci, J. Koutecky, J. Chem. Phys. 98, 7981 (1993)
A. Fortunelli (private communication)
Author information
Authors and Affiliations
Corresponding author
Additional information
Received: 24 November 2003, Published online: 10 February 2004
PACS:
61.46. + w Nanoscale materials: clusters, nanoparticles, nanotubes, and nanocrystals - 68.55.Ln Defects and impurities: doping, implantation, distribution, concentration, etc. - 79.20.Rf Atomic, molecular, and ion beam impact and interactions with surfaces - 81.05.Uw Carbon, diamond, graphite
Rights and permissions
About this article
Cite this article
Seminara, L., Convers, P., Monot, R. et al. Implantation of size-selected silver clusters into graphite. Eur. Phys. J. D 29, 49–56 (2004). https://doi.org/10.1140/epjd/e2004-00011-9
Issue Date:
DOI: https://doi.org/10.1140/epjd/e2004-00011-9