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Determination of transition dipole moments from time-resolved photoelectron spectroscopy

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Abstract.

We show how to extract the energy- and coordinate dependence of dipole-moments for a neutral-to-ionic molecular transition from time-resolved photoelectron spectra. The procedure needs the potential surfaces of the neutral and the cationic state which are involved in the ionization process as an input. Given these potentials and the laser parameters it is possible to determine the functional form of the transition dipole moment from the measured time- and energy-resolved transient signals.

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Authors and Affiliations

  1. Institut für Physikalische Chemie, Universität Würzburg, Am Hubland, 97074, Würzburg, Germany

    T. Lohmüller, M. Erdmann & V. Engel

  2. Institut für Nanotechnologie, Forschungszentrum Karlsruhe GmbH, Postfach 3640, 76021, Karlsruhe, Germany

    O. Rubner

Authors
  1. T. Lohmüller
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  2. M. Erdmann
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  3. O. Rubner
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  4. V. Engel
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Additional information

Received: 28 February 2003, Published online: 29 April 2003

PACS:

31.70.Hq Time-dependent phenomena: excitation and relaxation processes, and reaction rates - 33.80.Wz Other multiphoton processes

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Lohmüller, T., Erdmann, M., Rubner, O. et al. Determination of transition dipole moments from time-resolved photoelectron spectroscopy. Eur. Phys. J. D 25, 95–99 (2003). https://doi.org/10.1140/epjd/e2003-00094-8

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