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The role of additional anions in microporous aluminosilicates with cancrinite-type framework

  • Structure of Chemical Compounds. Spectroscopy
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Abstract

Microporous framework aluminosilicates with the cancrinite- and sodalite-type structures containing NO −3 , CO 2−3 , SO 2−4 and PO 3−4 , as extra-framework anions were synthesized under hydrothermal conditions at temperatures from 160 to 200°C. SO 2−4 exhibits the highest affinity to cancrinite structure at the competition of various X anions. Chemical composition, X-ray diffractometry characteristics, and IR spectra of the compounds obtained, as well as kinetics and mechanism of thermal transformations of nitrate counterpart of cancrinite, were studied.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Russia

    N. V. Chukanov, V. V. Nedelko, L. N. Blinova & L. A. Korshunova

  2. Department of Geology, Moscow State University, Moscow, Russia

    L. V. Olysych, I. S. Lykova & I. V. Pekov

  3. Department of Mineralogy, Munster University, Munster, Germany

    J. C. Buhl

  4. Institut fur Geowissenschaften, Christian-Albrecht Universitat, Kiel, Germany

    W. Depmeier

Authors
  1. N. V. Chukanov
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  2. V. V. Nedelko
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  3. L. N. Blinova
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  4. L. A. Korshunova
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  5. L. V. Olysych
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  6. I. S. Lykova
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  7. I. V. Pekov
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  8. J. C. Buhl
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  9. W. Depmeier
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Corresponding author

Correspondence to N. V. Chukanov.

Additional information

Original Russian Text © N.V. Chukanov, V.V. Nedelko, L.N. Blinova, L.A. Korshunova, L.V. Olysych, I.S. Lykova, I.V. Pekov, J.C. Buhl, W. Depmeier, 2012, published in Khimicheskaya Fizika, 2012, Vol. 31, No. 9, pp. 15–23.

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Chukanov, N.V., Nedelko, V.V., Blinova, L.N. et al. The role of additional anions in microporous aluminosilicates with cancrinite-type framework. Russ. J. Phys. Chem. B 6, 593–600 (2012). https://doi.org/10.1134/S1990793112050120

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  • DOI: https://doi.org/10.1134/S1990793112050120

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