Abstract
In this work, poly(methylene-xylene trisulfide) was synthesized using methylene dichloride, α,α′‑dichloro-p-xylene, and sodium trisulfide (Na2S3). Then, the nanocomposites of poly(methylene-xylene trisulfide) and Cloisite 30B were synthesized via in situ polymerization. The nanocomposite, sulfur, zinc oxide, stearic acid, and N-cyclohexyl-2-benzothiazole sulfenamide were compounded and cured. The polymer, nanocomposite and cured nanocomposite was characterized by Fourier transform infrared spectroscopy, X-ray diffraction, proton nuclear magnetic resonance spectroscopy, thermogravimetric analysis, differential scanning calorimetry, scanning electron microscopy, tensile test, and Shore A. After the curing process, the properties of the polymer improved and the melting point was not observed. By adding Cloisite 30B to the matrix and increasing its content, curing time, glass transition temperature, hardness, elastic modulus, and strength increased.
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Milad Sheydaei Synthesis, Characterization, Curing, Thermal and Mechanical Properties of Methylene-Xylene-Based Polysulfide Block Copolymer/Cloisite 30B Nanocomposites. Polym. Sci. Ser. B 65, 201–208 (2023). https://doi.org/10.1134/S1560090423700859
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DOI: https://doi.org/10.1134/S1560090423700859