Skip to main content
SpringerLink
Log in

Synthesis of Mixed Functional Oligoaryloxycyclotriphosphazenes

  • FUNCTIONAL POLYMERS
  • Published:
Polymer Science, Series B Aims and scope Submit manuscript

Abstract

Oligomeric aryloxycyclotriphosphazenes with mixed functional groups are synthesized by the interaction of hexachlorocyclotriphosphazene and two phenols, methyl-4-hydroxybenzoate (paraben) and 4‑allyl-2-methoxyphenol (eugenol), at different order of their introduction into the reaction mixture. The hydrolysis of ester groups of aryloxycyclotriphosphazenes yields corresponding carboxyphenoxycyclophosphazenes, and the oxidation of their allyl groups by m-chloroperbenzoic acid affords epoxy derivatives. Optimal conditions for the indicated transformations are determined, and structure of the resulting oligomers is studied by 1Н and 31Р NMR spectroscopy and MALDI-TOF mass spectrometry.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

REFERENCES

  1. A. Medici, G. Fantin, P. Pedrini, M. Gleria, and F. Minto, Macromolecules 25 (10), 2569 (1992).

    Article  CAS  Google Scholar 

  2. D. Alekperov, T. Shirosaki, T. Sahurai, G. Popova, V. Kireev, and H. Ihara, Polym. J. 35 (5), 417 (2003).

    Article  CAS  Google Scholar 

  3. V. Chandrasekhar, Inorganic and Organometallic Polymers (Springer Verlag, Berlin, 2005).

    Google Scholar 

  4. A. K. Andrianov, Polyphosphazenes for Biomedical Applications (Wiley: Hoboken, 2009).

    Book  Google Scholar 

  5. Phosphazenes: A Worldwide Insight, R. De. Jaeger and M. Gleria, Eds. (Nova Sci. Publ., New York, 2011), 2nd Quarter.

  6. V. V. Kireev, E. M. Chistyakov, S. N. Filatov, R. S. Borisov, and B. M. Prudskov, Polym. Sci., Ser. B 53 (7–8), 412 (2011)

  7. J. Liu, J. Tang, X. Wang, and D. Wu, RSC Adv. 2 (13), 5789 (2012).

    Article  CAS  Google Scholar 

  8. I. V. Terekhov, S. N. Filatov, E. M. Chistyakov, R. S. Borisov, and V. V. Kireev, Russ. J. Appl. Chem. 86 (10), 1600 (2013).

    Article  CAS  Google Scholar 

  9. I. S. Sirotin, Yu. V. Bilichenko, A. N. Solodukhin, V. V. Kireev, M. I. Buzin, and R. S. Borisov, Polym. Sci., Ser. B 55 (5–6), 241 (2013).

  10. I. S. Sirotin, Candidate’s Dissertation in Chemistry (Moscow, 2013).

Download references

Funding

This work was supported by the Ministry of Science and Higher Education of the Russian Federation within the framework of State Assignment (project no. FSSM-2022-0010).

Author information

Authors and Affiliations

  1. Mendeleev University of Chemical Technology of Russia, 125047, Moscow, Russia

    Yu. V. Bilichenko, Pham Van Thuan, R. S. Borisov & V. V. Kireev

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    R. S. Borisov

Authors
  1. Yu. V. Bilichenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Pham Van Thuan
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. R. S. Borisov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. V. Kireev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. V. Kireev.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by T. Soboleva

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bilichenko, Y.V., Van Thuan, P., Borisov, R.S. et al. Synthesis of Mixed Functional Oligoaryloxycyclotriphosphazenes. Polym. Sci. Ser. B 64, 855–862 (2022). https://doi.org/10.1134/S1560090422700610

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1560090422700610

Search

Navigation