Skip to main content
SpringerLink
Log in

Microporous Polymers Based on Rigid-Chain Di- And Triacetyl Aromatic Compounds

  • FUNCTIONAL POLYMERS
  • Published:
Polymer Science, Series B Aims and scope Submit manuscript

Abstract—

Polycondensation of rigid-chain di- and triacetylarenes and their copolycondensation has afforded three-dimensional polymers via the formation of 1,3,5-phentriyl and dipnone moieties. The influence of the monomers structure on the polymers properties has been analyzed. Additional thermal treatment at 450оC has afforded microporous polyphenylenes with phentriyl branching fragments exhibiting intrinsic surface area of 650–690 m2/g.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.

Similar content being viewed by others

REFERENCES

  1. F. Schüth, K. S. W. Sing, and J. Weitkamp, Handbook of Porous Solids (Wiley, Weinheim, 2002).

    Book  Google Scholar 

  2. L. J. Abbott and C. M. Colina, Macromolecules 44, 4511 (2011).

    Article  CAS  Google Scholar 

  3. D. Ramimoghadam, E. MacA Gray, and C. J. Webb, Int. J. Hydrogen Energy 41 (38), 16944 (2016).

    Article  CAS  Google Scholar 

  4. G. Bengtson, S. Neumann, and V. Filiz, Membranes, No. 2, 28 (2017).

  5. N. B. McKeown and P. M. Budd, Macromolecules 43, 5163 (2010).

    Article  CAS  Google Scholar 

  6. T. Ben, H. Ren, S. Q. Ma, D. P. Cao, J. H. Lan, X. F. Jing, W. C. Wang, J. Xu, F. Deng, J. M. Simmons, S. L. Qiu, G. S. Zhu, Angew. Chem. 48, 9457 (2009).

    Article  CAS  Google Scholar 

  7. J. Schmidt, M. Werner, and A. Thomas, Macromolecules 42 (13), 4426 (2009).

    Article  CAS  Google Scholar 

  8. J. Weber and A. Thomas, J. Am. Chem. Soc. 130, 6334 (2008).

    Article  CAS  Google Scholar 

  9. S. W. Yuan, S. Kirklin, B. Dorney, D. J. Liu, L. P. Yu, Macromolecules 42, 1554 (2009).

    Article  CAS  Google Scholar 

  10. A. I. Kovalev, E. S. Mart’yanova, I. A. Khotina, Z. S. Klemenkova, Z. K. Blinnikova, E. V. Volchkova, T. P. Loginova, I. I. Ponomarev, Polym. Sci., Ser B 60 (5), 675 (2018).

    Article  CAS  Google Scholar 

  11. I. A. Khotina, O. A. Filippov, and A. I. Kovalev, Mendeleev Commun. 30 (3), 366 (2020).

    Article  CAS  Google Scholar 

  12. A. I. Kovalev, A. V. Pastukhov, E. S. Tkachenko, Z. S. Klemenkova, I. R. Kuvshinov, I. A. Khotina, Polym. Sci., Ser. C 62 (2), 205 (2020).

    Article  CAS  Google Scholar 

  13. A. I. Kovalev, Yu. I. Lyakhovetskii, M. M. Teplyakov, A. L. Rusanov, P. V. Petrovskii, S. O. Yakushin, Russ. Chem. Bull 42 (9), 1529 (1993).

    Article  Google Scholar 

  14. I. A. Khotina, O. E. Shmakova, D. Yu. Baranova, N. S. Burenkova, A. A. Gurskaja, P. M. Valetsky, L. M. Bronstein, Macromolecules 36 (22), 8353 (2003).

    Article  CAS  Google Scholar 

  15. N. E. Bukhnova and A. P. Karnaukhov, Opredelenie Udel’noi Poverkhnosti Tverdykh Tel Khromatograficheskim Metodom Teplovoi Desorbtsii Argona (Determining Specific Surface Area by Chromatographic Method of Heat-Induced Argon Desorption), (Nauka, Novosibirsk, 1965) [in Russian].

    Google Scholar 

  16. T. L. Jacobs and M. H. Goodrow, Org. Chem. 23, 1653 (1958).

    Article  CAS  Google Scholar 

Download references

ACKNOWLEDGMENTS

The NMR experiments were supported by the Ministry of Science and Higher Education of Russian Federation and performed using the equipment of the Center for the Study of Molecular Structure, Institute of Organoelement Compounds, RAS.

Funding

This study was financially supported by the Russian Foundation for Basic Research (project code 20-03-00087).

Author information

Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    A. I. Kovalev, S. A. Babich, M. A. Kovaleva, N. S. Kushakova, Z. S. Klemenkova, Z. K. Blinnikova, A. Yu. Popov & I. A. Khotina

Authors
  1. A. I. Kovalev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. A. Babich
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. A. Kovaleva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. S. Kushakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Z. S. Klemenkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Z. K. Blinnikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. Yu. Popov
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. I. A. Khotina
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. I. Kovalev.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by E. Karpushkin

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kovalev, A.I., Babich, S.A., Kovaleva, M.A. et al. Microporous Polymers Based on Rigid-Chain Di- And Triacetyl Aromatic Compounds. Polym. Sci. Ser. B 64, 155–160 (2022). https://doi.org/10.1134/S156009042201002X

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S156009042201002X

Search

Navigation