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Microstructure of Polymers Prepared in the Presence of Tri-n-butylboron–p-Quinone System

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Abstract

The microstructure of polystyrene, poly(methyl acrylate), and poly(tert-butyl acrylate) obtained in the presence of tri-n-butylboron in combination with naphthoquinone-1,4 and 2,3-dimethylbenzoquinone is studied. The stereoregularity of polymers formed under these conditions may be described in the framework of the first-order Markov chain model. The use of p-quinones in combination with tri-n-butylboron favors an increase in the content of isotactic triads in the polymers. The causes of the observed deviations are discussed.

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Authors and Affiliations

  1. Nizhny Novgorod State University, Nizhny Novgorod, 603950, Russia

    D. V. Ludin, Yu. L. Kuznetsova & S. D. Zaitsev

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  1. D. V. Ludin
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  2. Yu. L. Kuznetsova
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  3. S. D. Zaitsev
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Correspondence to D. V. Ludin.

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Original Russian Text © D.V. Ludin, Yu.L. Kuznetsova, S.D. Zaitsev, 2018, published in Vysokomolekulyarnye Soedineniya, Seriya B, 2018, Vol. 60, No. 5, pp. 357–364.

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Ludin, D.V., Kuznetsova, Y.L. & Zaitsev, S.D. Microstructure of Polymers Prepared in the Presence of Tri-n-butylboron–p-Quinone System. Polym. Sci. Ser. B 60, 541–548 (2018). https://doi.org/10.1134/S1560090418050093

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  • DOI: https://doi.org/10.1134/S1560090418050093

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