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Specific features of radical copolymerization of methyl methacrylate and n-butyl acrylate in the presence of the tributylborane–p-quinone system

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Abstract

Copolymerization of methyl methacrylate (MMA) and n-butyl acrylate (n-BA) in the presence of the tributylborane–p-quinone system has been investigated. Reactivity ratios of the monomers differ from the values known for conventional radical polymerization. The copolymerization proceeds in a controlled manner according to the reversible inhibition mechanism. The nature of p-quinone and the composition of the monomer mixture affect the realization of this mechanism. The microstructure of the copolymers obtained in the presence of borane and p-quinones depends on the nature of the latter.

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Authors and Affiliations

  1. Lobachevsky State University of Nizhny Novgorod, Nizhny Novgorod, 603950, Russia

    D. V. Ludin, Yu. L. Kuznetsova & S. D. Zaitsev

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  1. D. V. Ludin
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  2. Yu. L. Kuznetsova
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  3. S. D. Zaitsev
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Correspondence to D. V. Ludin.

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Original Russian Text © D.V. Ludin, Yu.L. Kuznetsova, S.D. Zaitsev, 2017, published in Vysokomolekulyarnye Soedineniya, Seriya B, 2017, Vol. 59, No. 5, pp. 337–347.

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Ludin, D.V., Kuznetsova, Y.L. & Zaitsev, S.D. Specific features of radical copolymerization of methyl methacrylate and n-butyl acrylate in the presence of the tributylborane–p-quinone system. Polym. Sci. Ser. B 59, 516–525 (2017). https://doi.org/10.1134/S1560090417050086

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  • DOI: https://doi.org/10.1134/S1560090417050086

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