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Effect of Cadmium Ions on the Growth of CsPbxCD1 – xBr3 Nanocrystals in Fluorophosphate Glass

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Abstract

Perovskite CsPbxCD1 – xBr3 nanocrystals were first synthesized in fluorophosphate glass. It has been found that the incorporation of cadmium ions into the perovskite structure leads to a shift of the luminescence band from 525 to 464 nm, as a result of which the emission color changes from green to blue. A further increase in the concentration of cadmium leads to the growth of CsCdBr3 nanocrystals, which do not have their own luminescence, in the hexagonal phase.

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REFERENCES

  1. Protesescu, L., Yakunin, S., Bodnarchuk, M.I., Krieg, F., Caputo, R., Hendon, C.H., Yang, R.X., Walsh, A., and Kovalenko, M.V., Nanocrystals of cesium lead halide perovskites (CsPbX3, X = Cl, Br, and I): Novel optoelectronic materials showing bright emission with wide color gamut, Nano Lett., 2015, vol. 15, pp. 3692–3696.

    Article  CAS  Google Scholar 

  2. Li, X., Cao, F., Yu, D., Chen, J., Sun, Z., Shen, Y., Zhu, Y., Wang, L., Wei, Y., Wu, Y., and Zeng, H., All inorganic halide perovskites nanosystem: Synthesis, structural features, optical properties and optoelectronic applications, Small, 2015, vol. 13, p. 1603996.

    Article  Google Scholar 

  3. Kovalenko, M.V., Protesescu, L., and Bodnarchuk, M.I., Properties and potential optoelectronic applications of lead halide perovskite nanocrystals, Science (Washington, DC, U. S.), 2017, vol. 358, pp. 745–750.

    Article  CAS  Google Scholar 

  4. Yuan, S., Chen, D., Li, X., Zhong, J., and Xu, X., In situ crystallization synthesis of CsPbBr3 perovskite quantum dots embedded glasses with improved stability for solid-state-lighting and random upconverted lasing, ACS Appl. Mater. Interfaces, 2018, vol. 10, pp. 18918–18926.

    Article  CAS  Google Scholar 

  5. Chen, D., Yuan, S., Chen, X., Li, J., Mao, Q., Li, X., and Zhong, J., CsPbX3 (Cl, Br, I) perovskite quantum dots embedded low-melting phosphosilicate glasses: Controllable crystallization, thermal stability and tunable emissions, J. Mater. Chem. C, 2018, vol. 6, pp. 6832–6839.

    Article  CAS  Google Scholar 

  6. Akkerman, Q.A., Rain, G., Kovalenko, M.V., and Manna, L., Genesis, challenges and opportunities for colloidal lead halide perovskite nanocrystals, Nat. Mater., 2018, vol. 17, pp. 394–405.

    Article  CAS  Google Scholar 

  7. Sun, C., Zhang, Y., Ruan, C., Yin, C., Wang, X., Wang, Y., and Yu, W.W., Efficient and stable white LEDs with silica-coated inorganic perovskite quantum dots, Adv. Mater., 2016, vol. 28, pp. 10088–10094.

    Article  CAS  Google Scholar 

  8. Kazim, S., Nazeeruddin, M.K., Grätzel, M., and Ahmad, S., Perovskite as light harvester: A game changer in photovoltaics, Angew. Chem., Int. Ed. Engl., 2014, vol. 53, pp. 2812–2824.

    Article  CAS  Google Scholar 

  9. Shekhirev, M., Goza, J., Teeter, J.D., Lipatov, A., and Sinitskii, A., Synthesis of cesium lead halide perovskite quantum dots, J. Chem. Educ., 2017, vol. 94, pp. 1150–1156.

    Article  CAS  Google Scholar 

  10. Swarnkar, A., Kumar Ravi, V., Chulliyil, R., Irfanullah, M., Chowdhury, A., and Nag, A., Colloidal CsPbBr3 perovskite nanocrystals: Luminescence beyond traditional quantum, Chem. Int. Ed., 2015, vol. 54, pp. 15424–15428.

    Article  CAS  Google Scholar 

  11. Yuan, X., Ji, S., de Siena, M.C., Fei, L., Zhao, Z., Wang, Y., Li, H., Zhao, J., and Gamelin, D.R., Photoluminescence temperature dependence, dynamics, and quantum efficiencies in Mn2+-doped CsPbCl3 perovskite nanocrystals with varied dopant concentration, Chem. Mater., 2017, vol. 29, pp. 8003–8011.

    Article  CAS  Google Scholar 

  12. Pan, G., Bai, X., Yang, D., Chen, X., Jing, P., Qu, S., Zhang, L., Zhou, D., Zhu, J., Xu, W., Dong, B., and Song, H., Doping lanthanide into perovskite nanocrystals: Highly improved and expanded optical properties, Nano Lett., 2017, vol. 17, pp. 8005–8011.

    Article  CAS  Google Scholar 

  13. Zhou, Y., Chen, J., Bakr, O.M., and Sun, H., Metal-doped lead halide perovskites: Synthesis, properties, and optoelectronic applications, Chem. Mater., 2018, vol. 30, pp. 6589–6613.

    Article  CAS  Google Scholar 

  14. Wang, A., Yan, X., Zhang, M., Sun, S., Yang, M., Shen, W., Pan, X., Wang, P., and Deng, Z., Controlled synthesis of lead-free and stable perovskite derivative Cs2SnI6 nanocrystals via facile hot-injection process, Chem. Mater., 2016, vol. 28, pp. 8132–8140.

    Article  CAS  Google Scholar 

  15. Van der Stam, W., Geuchies, J.J., Altantzis, T., Bos, K.H.W., Meeldijk, J.D., Aert, S.V., Bals, S., Vanmaekelbergh, D., and Donega, C.M., Highly emissive divalent-ion-doped colloidal CsPb1 – xMxBr3 perovskite nanocrystals through cation exchange, J. Am. Chem. Soc., 2017, vol. 139, pp. 4087–4097.

    Article  CAS  Google Scholar 

  16. Ai, B., Liu, C., Wang, J., Xie, J., Han, J., and Zhao, X., Precipitation and optical properties of CsPbBr3 quantum dots in phosphate glasses, J. Am. Ceram. Soc., 2016, vol. 99, pp. 2875–2877.

    Article  CAS  Google Scholar 

  17. Zhao, Y., Shen, C., Ding, L., Liu, J., Xiang, W., and Liang, X., Novel B-site Cd2+ doped CsPbBr3 quantum dot glass toward strong fluorescence and high stability for w-LED, Opt. Mater., 2020, vol. 107, p. 110046.

    Article  CAS  Google Scholar 

  18. Shapiro, A., Heindl, M.W., Horani, F., Dahan, M.H., Tang, J., Amouyal, Y., and Lifshitz, E., Significance of Ni doping in CsPbX3 nanocrystals via post synthesis cation-anion coexchange, J. Phys. Chem. C, 2019, vol. 123, pp. 24979–24987.

    Article  CAS  Google Scholar 

  19. Zhao, Y., Zhang, X., Xie, C., Shi, W., Yang, P., and Jiang, S.P., Controlling Mn emission in CsPbCl3 nanocrystals via ion exchange toward enhanced and tunable white photoluminescence, Phys. Chem. C, 2020, vol. 124, pp. 27032–27039.

    Article  CAS  Google Scholar 

  20. Akkerman, Q.A., Meggiolaro, D., Dang, Z., de Angelis, F., and Manna, L., Fluorescent alloy CsPbxMn1 – xI3 perovskite nanocrystals with high structural and optical stability, ACS Energy Lett., 2017, vol. 2, pp. 2183–2186.

    Article  CAS  Google Scholar 

  21. Cai, T., Yang, H.J., Hills-Kimball, K., Song, J.P., Zhu, H., Hofman, E., Zheng, W.W., Rubenstein, B.M., and Chen, O., Synthesis of all-inorganic Cd-doped CsPbCl3 perovskite nanocrystals with dual-wavelength emission, J. Phys. Chem. Lett., 2018, vol. 9, pp. 7079–7084.

    Article  CAS  Google Scholar 

  22. Zou, S., Liu, Y., Li, J., Liu, C., Feng, R., Jiang, F., Li, Y., Song, J., Zeng, H., Hong, M., and Chen, X., Stabilizing cesium lead halide perovskite lattice through Mn(II) substitution for air-stable light-emitting diodes, J. Am. Chem. Soc., 2017, vol. 139, pp. 11443–11450.

    Article  CAS  Google Scholar 

  23. Kuznetsova, M.S., Cherbunin, R.V., Litvyak, V.M., and Kolobkova, E.V., Spectroscopy of PbS and PbSe quantum dots in fluorine phosphate glasses, Semiconductors, 2018, vol. 52, pp. 558–561.

    Article  CAS  Google Scholar 

  24. Kolobkova, E.V., Lipovskii, A.A., Petrikov, V.D., and Melekhin, V.G., Fluorophosphate glasses with quantum dots based on lead sulfide, Glass Phys. Chem., 2002, vol. 28, pp. 251–255.

    Article  CAS  Google Scholar 

  25. Vaynberg, B., Matusovsky, M., Rosenbluh, M., Kolobkova, E., and Lipovskii, A., High optical nonlinearity of CdSxSe1 – x microcrystals in fluorine-phosphate glass, Opt. Commun., 1996, vol. 132, pp. 307–310.

    Article  CAS  Google Scholar 

  26. Lipovskii, A.A., Yakovlev, I.E., Kolobkova, E.V., and Petrikov, V.D., Formation and growth of semiconductor nanocrystals in phosphate glass matrix, J. Eur. Ceram. Soc., 1999, vol. 19, pp. 865–869.

    Article  CAS  Google Scholar 

  27. Kolobkova, E.V., Kuznetsova, M.S., and Nikonorov, N.V., Perovskite CsPbX3 (X = Cl, Br, I) nanocrystals in fluorophosphate glasses, J. Non-Cryst. Solids, 2021, vol. 563, p. 120811.

    Article  CAS  Google Scholar 

  28. Liu, S., de Filippo, A.R., Balasubramanian, M., Liu, Z.X., Wang, S.G., Chen, Y., Chariton, S., Prakapenka, V., Luo, X.P., Zhao, L.Y., San Martin, J., Lin, Y.X., Yan, Y., Ghose, S.K., and Tyson, T.A., High-resolution in-situ synchrotron X-ray studies of inorganic perovskite CsPbBr3: New symmetry assignments and structural phase transitions, Adv. Sci., 2021, vol. 8, p. 2003046.

    Article  CAS  Google Scholar 

  29. Luo, X., Lai, R., Li, Y., Han, Y., Liang, G., Liu, X., Ding, T., Wang, J., and Wu, K., Triplet energy transfer from CsPbBr3 nanocrystals enabled by quantum confinement, J. Am. Chem. Soc., 2019, vol. 141, pp. 4186–4190.

    Article  CAS  Google Scholar 

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AKNOWLEDGMENTS

This research was supported by Priority 2030 Federal Academic Leadership Program. M.S.K. thanks the St. Petersburg State University Research Grant no. 91182694.

Funding

This work was supported by the Russian Science Foundation (grant no. 19-13-00343).

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Authors and Affiliations

  1. St. Petersburg State Technological Institute (Technical University), 190013, St. Petersburg, Russia

    E. V. Kolobkova & A. Yu. Dadykin

  2. ITMO University, 199034, St. Petersburg, Russia

    E. V. Kolobkova & A. V. Makurin

  3. Spin Optics Laboratory, St. Petersburg State University, 198504, St. Petersburg, Russia

    M. S. Kuznetsova

Authors
  1. E. V. Kolobkova
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  2. A. V. Makurin
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  3. A. Yu. Dadykin
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  4. M. S. Kuznetsova
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Correspondence to E. V. Kolobkova.

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Based on the Report at the Third Russian Conference with International Participation “Glass: Science and Practice” GlasSP2021 (St. Petersburg, September 13–17, 2021)

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Kolobkova, E.V., Makurin, A.V., Dadykin, A.Y. et al. Effect of Cadmium Ions on the Growth of CsPbxCD1 – xBr3 Nanocrystals in Fluorophosphate Glass. Glass Phys Chem 48, 403–409 (2022). https://doi.org/10.1134/S1087659622800070

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