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Mineralogy and formation conditions of ores in the Bereznyakovskoe ore field, the Southern Urals, Russia

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Abstract

The Bereznyakovskoe ore field is situated in the Birgil’da-Tomino ore district of the East Ural volcanic zone. The ore field comprises several centers of hydrothermal mineralization, including the Central Bereznyakovskoe and Southeastern Bereznyakovskoe deposits, which are characterized in this paper. The disseminated and stringer-disseminated orebodies at these deposits are hosted in Upper Devonian-Lower Carboniferous dacitic-andesitic tuff and are accompanied by quartz-sericite hydrothermal alteration. Three ore stages are recognized: early ore (pyrite); main ore (telluride-base-metal, with enargite, fahlore-telluride, and gold telluride substages); and late ore (galena-sphalerite). The early and the main ore stages covered temperature intervals of 320–380 to 180°C and 280–300 to 170°C, respectively; the ore precipitated from fluids with a predominance of NaCl. The mineral zoning of the ore field is expressed in the following change of prevalent mineral assemblages from the Central Bereznyakovskoe deposit toward the Southeastern Bereznyakovskoe deposit: enargite, tennantite, native tellurium, tellurides, and selenides → tennantite-tetrahedrite, tellurides, and sulfoselenides (galenoclausthalite) → tetrahedrite, tellurides, native gold, galena, and sphalerite. The established trend of mineral assemblages was controlled by a decrease in \( f_{S_2 } \), \( f_{Te_2 } \) and \( f_{O_2 } \) and an increase in pH of mineral-forming fluids from early to late assemblages and from the Central Bereznyakovskoe deposit toward the Southeastern Bereznyakovskoe deposit. Thus, the Central Bereznyakovskoe deposit was located in the center of an epithermal high-sulfidation ore-forming system. As follows from widespread enargite and digenite, a high Au/Ag ratio, and Au-Cu specialization of this deposit, it is rather deeply eroded. The ore mineralization at the Southeastern Bereznyakovskoe deposit fits the intermediate- or low-sulfidation type and is distinguished by development of tennantite, a low Au/Ag ratio, and enrichment in base metals against a lowered copper content. In general, the Bereznyakovskoe ore field is a hydrothermal system with a wide spectrum of epithermal mineralization styles.

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References

  1. A. M. Afifi, W. C. Kelly, and J. Essene, “Phase Relations among Tellurides, Sulfides, and Oxides: I. Thermochemical Data and Calculated Equilibria,” Econ. Geol. 83, 377–394 (1988).

    Article  Google Scholar 

  2. A. V. Akimova and O. Yu. Plotinskaya, “Morphology and Internal Structure of Pyrite of the Bereznyakovskoe Gold Deposit, the Southern Urals,” in Proceedings of Scientific Conference Dedicated to Centenary of F.V. Chukhrov (IGEM, Moscow, 2008), pp. 244–246.

    Google Scholar 

  3. A. V. Akimova, A. V. Mokhov, and O. Yu. Plotinskaya, “The First Find of Natural Brass in the Bereznyakovskoe Epithermal Gold Deposit, the Southern Urals,” in Proceedings of International Scientific Conference. Fedorov Session 2008 (Russian Mineral. Soc., St. Petersburg, 2008), pp. 238–240.

    Google Scholar 

  4. R. A. Amosov and S. L. Vasin, Ontogeny of Natural Gold of Russia (TsNIGRI, Moscow, 1995) [in Russian].

    Google Scholar 

  5. P. B. Barton, Jr. and B. J. Skinner, “Sulfide Mineral Stabilities,” in Geochemistry of Hydrothermal Ore Deposits (Wiley, New York, 1979), pp. 278–403.

    Google Scholar 

  6. R. J. Bodnar and M. O. Vityk, “Interpretation of Microthermometric Data for H2O-NaCl Fluid Inclusions,” in Fluid Inclusions in Minerals: Methods and Applications (Pontignano, Siena, 1994), pp. 117–130.

    Google Scholar 

  7. A. S. Borisenko, “The Study of Salt Composition of Fluid Inclusions in Minerals by Cryometric Method,” Geol. Geofiz. 18(8), 16–27 (1977).

    Google Scholar 

  8. N. S. Bortnikov, H. Kramer, A. D. Genkin, et al., “Parageneses of Gold and Silver Tellurides in the Florencia Gold Deposit, the Republic of Cuba,” Geol. Rudn. Mestorozhd., vol. 30, No. 2, 49–61 (1988).

    Google Scholar 

  9. I. B. Butler and D. Rickard, “Framboidal Pyrite Formation Via Oxidation of Iron (II) Monosulfide by Hydrogen Sulfide,” Geochim. Cosmochim. Acta 64(15), 2665–2675 (2000).

    Article  Google Scholar 

  10. L. J. Cabri, “Phase Relations in the Au-Ag-Te System and Their Mineralogical Significance,” Econ. Geol. 60, 1569–1606 (1965).

    Article  Google Scholar 

  11. C. Ciobanu, N. J. Cook, G. Damian, et al., “Telluride and Sulphosalt Associations at Sacarimb,” in Gold-Silver-Telluride Deposits of the Quadrilateral, South Apuseni Mts., Alba Luliai, IACOD Guidebook Series (Romania, 2004), pp.145–186.

  12. B. M. England and J. Ostwald, “Framboid-Derived Structures in Some Tasman Fold Belt Base Metal Sulfide Deposits, New-South-Wales, Australia,” Ore Geol. Rev. 7, 381–412 (1993).

    Article  Google Scholar 

  13. A. I. Grabezhev, Ore-Geochemical Porphyry Copper Systems in the Northern Part of the Uvel’sky Zone (Inst. Geol. Geochim. Ural Division, Russian Acad. Sci., Yekaterinburg, 1992) [in Russian].

    Google Scholar 

  14. A. I. Grabezhev and A. A. Krasnobaev, “U-Pb Age and Isotopic Geochemical Characteristic of the Tomino-Bereznyakovskoe Ore Field, the Southern Urals,” Litosfera, No. 2, 14–27 (2009).

  15. A. I. Grabezhev and V. P. Moloshag, “Zinc-Copper-Silver-Gold Mineralization of the Tomino Porphyry Copper Center, the Southern Urals,” Dokl. Akad. Nauk 330(3), 349–351 (1993).

    Google Scholar 

  16. A. I. Grabezhev, N. S. Kuznetsov, and B. A. Puzhakov, Ore-Metasomatic Zoning of the Sodium-Type Porphyry Copper Column (Paragonite-Bearing Halos, the Urals) (UGGGA, Yekaterinburg, 1998) [in Russian].

    Google Scholar 

  17. A. I. Grabezhev, V. N. Sazonov, V. V. Murzin, V. P. Moloshag, V. I. Sotnikov, N. S. Kuznetsov, B. A. Puzhakov, and B. G. Pokrovsky, “The Bereznyakovskoe Gold Deposit, the South Urals, Russia,” Geol. Rudn. Mestorozhd. 42(1), 38–52 (2000) [Geol. Ore Deposits 42 (1), 33–46 (2000)].

    Google Scholar 

  18. R. J. Herrington, V. V. Zaykov, V. V. Maslennikov, et al., “Mineral Deposits of the Urals and Links to Geodynamic Evolution,” Econ. Geol. 100, 1069–1095 (2005).

    Google Scholar 

  19. R. R. Jannas, R. E. Beane, B. A. Ahler, and D. R. Brosnahan, “Gold and Copper Mineralization at the El Indio Deposit, Chile,” J. Geoch. Explor. 36, 233–266 (1990).

    Article  Google Scholar 

  20. J. Kalliokoski, “Pyrite Framboid: Animal, Mineral, or Vegetable?” Geology 2, 26–27 (1974).

    Article  Google Scholar 

  21. A. F. Kisters, “The Bereznjakovskoe Gold Trend, Southern Urals, Russia: A Discussion,” Miner. Deposita 35(4), 385–387 (2000).

    Article  Google Scholar 

  22. V. A. Koroteev, H. de Boorder, V. M. Necheukhin, and V. N. Sazonov, “Geodynamic Setting of the Mineral Deposits of the Urals,” Tectonophysics 276, 291–300 (1997).

    Article  Google Scholar 

  23. V. A. Kovalenker, “Typomorphic Minerals of Ores of Shallow-Seated Gold-Silver Deposits in the Upper Paleozoic Volcanic Region of Central Asia,” in Metasomatism, Mineralogy, and Genesis of the Gold and Silver Deposits in Volcanic Sequences (Nauka, Moscow, 1986), pp. 111–145 [in Russian].

    Google Scholar 

  24. V. A. Kovalenker, I. Ya. Nekrasov, and V. S. Malov, “Mineralogy and Parageneses of the Cu and Fe Sulfostannates at the Gold-Silver Deposits,” Geol. Rudn. Mestorozhd. 28(2), 67–84 (1986).

    Google Scholar 

  25. V. A. Kovalenker, O. Yu. Plotinskaya, and R. I. Koneev, “Mineralogy of Epithermal Gold-Sulfide-Telluride Ore at the Kairagach Deposit, Uzbekistan,” Nov. Dannye Mineral., No. 37, 45–63 (2003a).

  26. V. A. Kovalenker, O. Yu. Plotinskaya, V. Yu. Prokof’ev, Yu. L. Gertman, R. I. Koneev, and V. V. Pomortsev, “Mineralogy, Geochemistry, and Genesis of Gold-Sulfide-Selenide-Telluride Ores from the Kairagach Deposit, Uzbekistan,” Geol. Rudn. Mestorozhd. 45(3), 195–227 (2003b) [Geol. Ore Deposits 45 (3), 171–200 (2003)].

    Google Scholar 

  27. V. A. Kovalenker, Yu. G. Safonov, V. B. Naumov, and V. L. Rusinov, “Epithermal Gold-Telluride Kochbulak Deposit, Uzbekistan,” Geol. Rudn. Mestorozhd. 39(2), 127–152 (1997) [Geol. Ore Deposits 39 (2), 107–128 (1997)].

    Google Scholar 

  28. B. Lehmann and A. I. Grabezhev, “The Bereznjakovskoe Gold Trend, Southern Urals, Russia: A Reply,” Miner. Deposita 35(4), 388–389 (2000).

    Article  Google Scholar 

  29. B. Lehmann, J. Heinhorst, U. Hein, et al., “The Bereznjakovskoe Gold Trend, Southern Urals, Russia,” Miner. Deposita 34, 241–249 (1999).

    Article  Google Scholar 

  30. S. Maske and B. J. Skinner, “Studies of the Sulfosalts of Copper: I. Phases and Phase Relations in the System Cu-As-S,” Econ. Geol. 66, 901–918 (1971).

    Article  Google Scholar 

  31. V. P. Moloshag, A. I. Grabezhev, and T. Ya. Gulyaeva, “Gold-Tellurium-Telluride Assemblage of the Bereznyakovskoe Deposit, the Southern Urals,” in Yearbook-1992 (Inst. Geol. Geochim., Yekateriburg 1993), pp. 109–110.

    Google Scholar 

  32. R. Moritz, K. Kouzmanov, and R. Petrunov, “Late Cretaceous Cu-Au Epithermal Deposits of the Panagyurishte District, Srednogorie Zone, Bulgaria,” Shweiz. Mineral. Petrogr. Mitt. 84, 79–99 (2004).

    Google Scholar 

  33. V. V. Murzin, V. N. Sazonov, and V. V. Fedoseev, “Mineral Assemblages and PTX Formation Conditions of Ore at the Bereznyakovskoe Gold Deposit, the Southern Urals,” Yearbook-1993 (Inst. Geol. Geochim., Yekateriburg, 1994), 138–141.

    Google Scholar 

  34. V. V. Murzin, V. N. Sazonov, and V. V. Fedoseev, “Rare Minerals in Ore of the Bereznyakovskoe Gold Deposit, the Southern Urals,” Ural. Mineral. Sb., No. 5, 216–222 (1995).

  35. K. A. Novoselov, I. A. Savinov, E. V. Belogub, and V. A. Kotlyarov, “Enargite-Tennantite Ore of the Bereznyakovskoe Gold Deposit (Southern Ural),” in Metallogeny of Ancient and Modern Oceans-2003. Formation and Developmentn of Deposits in the Island-Arc Systems (Inst. Mineral., Ural Division, Russian Acad. Sci., Miass, 2003), pp. 177–183 [in Russian].

    Google Scholar 

  36. K. A. Novoselov, V. A. Kotlyarov, I. A. Savinov, and E. V. Belogub, “Mineralogical Zoning of Conduits from the Bereznyakovskoe Deposit, the Southern Urals,” Ural. Mineral. Sb., No. 13, 176–184 (2005).

  37. H. Ohfuji and D. Richard, “Experimental Syntheses of Framboids: A Review,” Earth Sci. Rev. 71, 147–170 (2005).

    Article  Google Scholar 

  38. D. V. Pals and P. G. Spry, “Telluride Mineralogy of the Low-Sulfidation Epithermal Emperor Gold Deposit, Vatukoula, Fiji,” Mineral. Petrol. 79, 285–307 (2003).

    Article  Google Scholar 

  39. O. Yu. Plotinskaya, K. A. Novoselov, R. Seltmann, et al., “Te and Se Mineralogy of the Bereznjakovskoe Deposit (South Urals),” in Proceedings of the IGCP Project 486 Field Workshop on Au-Ag-Telluride-Selenide Deposits (Dokuz Yelul Univ., Izmir, 2006b), pp. 137–144.

    Google Scholar 

  40. O. Yu. Plotinskaya, V. A. Kovalenker, R. Seltmann, and C. J. Stanley, “Te and Se Mineralogy of the Kochbulak and Kairagach High-Sulfidation Epithermal Gold Telluride Deposits (Kurama Ridge, Middle Tien Shan, Uzbekistan),” Mineral. Petrol. 87(3–4), 187–207 (2006a).

    Article  Google Scholar 

  41. B. A. Puzhakov and N. S. Kuznetsov, “The Bereznyakovskoe Gold Porphyry Deposit, the Southern Urals, in Proceedings of International Conference on Ore Formation (Inst. Mineral., Ural Division, Russian Acad. Sci., Miass, 2008), pp. 257–260.

    Google Scholar 

  42. D. T. Rickard, “The Origin of Framboids,” Lithos 3, 269–293 (1970).

    Article  Google Scholar 

  43. E. Roedder, Fluid Inclusions in Minerals (Reviews in Mineralogy, Mineral. Soc. Amer., 1984, Vol. 12; Mir, Moscow, 1987).

  44. L. N. Romashova, “The Birgil’da Porphyry Copper Deposit,” Geol. Rudn. Mestorozhd. 26(2), 20–30 (1984).

    Google Scholar 

  45. I. A. Savinov, “Geochemistry of Gold and Silver of the Southeastern Satellite of the Bereznyakovskoe Gold Deposit, the Southern Urals,” in Metallogeny of Ancient and Modern Ocean—2004 (Inst. Mineral., Ural Division, Russian Acad. Sci., Miass, 2004), Vol. 2, pp. 35–39 [in Russian].

    Google Scholar 

  46. V. N. Sazonov, V. N. Ogorodnikov, V. A. Koroteev, and Yu. A. Polenov, Gold Deposits of the Urals (UGGGA, Yekaterinburg, 2001) [in Russian].

    Google Scholar 

  47. V. N. Sazonov, V. V. Murzin, and N. A. Grigor’ev, The Bereznyakovskoe Porphyry Gold Deposit, the Southern Urals (Inst. Geol. Geochim. Ural Division, Russian Acad. Sci., Yekaterinburg, 1994) [in Russian].

    Google Scholar 

  48. R. H. Sillitoe and J. W. Hedenquist, “Linkages between Volcanotectonic Settings, Ore-Fluid Compositions, and Epithermal Precious Metal Deposits,” SEG Spec. Publ. 10, 315–343 (2003).

    Google Scholar 

  49. R. H. Sillitoe, “Epithermal Models: Genetic Types, Geometrical Controls and Shallow Features,” Geol. Assoc. Canada Spec. Paper 40, 403–417 (1993).

    Google Scholar 

  50. E. M. Spiridonov, A. I. Ignatov, and E. V. Shubina, “Evolution of Fahlore at the Ozernovskoe Volcanogenic Deposit, Kamchatka,” Izv. Akad. Nauk SSSR, Ser. Geol., No. 9, 82–94 (1990).

  51. A. S. Talantsev, Geothermobarometry from Dolomite-Calcite Parageneses (Nauka, Moscow, 1981) [in Russian].

    Google Scholar 

  52. R. T. Wilkin and H. L. Barnes, “Formation Processes of Framboidal Pyrite,” Geochim. Cosmochim. Acta 61(2), 323–339 (1997).

    Article  Google Scholar 

  53. R. T. Wilkin, H. L. Barnes, and S. L. Brantley, “The Size Distribution of Framboidal Pyrite in Modern Sediments: An Indicator of Redox Conditions,” Geochim. Cosmochim. Acta 60(20), 3897–3912 (1996).

    Article  Google Scholar 

  54. X. Zhang and P. G. Spry, “Calculated Stability of Aqueous Tellurium Species, Calaverite and Hessite at Elevated Temperature,” Econ. Geol. 89, 1152–1166 (1994).

    Article  Google Scholar 

  55. L. P. Zonnenshain, M. I. Kuz’min, and L. M. Natapov, Tectonics of Lithospheric Plates in Territory of the USSR (Nedra, Moscow, 1990) [in Russian].

    Google Scholar 

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Authors and Affiliations

  1. Institute of Geology of Ore Deposits, Petrography, Mineralogy, and Geochemistry, Russian Academy of Sciences, Staromonetnyi per. 35, Moscow, 119017, Russia

    O. Yu. Plotinskaya, E. O. Groznova & V. A. Kovalenker

  2. Institute of Mineralogy, Ural Division, Russian Academy of Sciences, Miass, Chelyabinsk oblast, 456317, Russia

    K. A. Novoselov

  3. CERCAMS, Department of Mineralogy, Natural History Museum, Cromwell Road, London, SW7 5BD, UK

    R. Seltmann

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  1. O. Yu. Plotinskaya
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  2. E. O. Groznova
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  3. V. A. Kovalenker
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  4. K. A. Novoselov
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Original Russian Text © O.Yu. Plotinskaya, E.O. Groznova, V.A. Kovalenker, K.A. Novoselov, R. Seltmann, 2009, published in Geologiya Rudnykh Mestorozhdenii, 2009, Vol. 51, No. 5, pp. 414–443.

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Plotinskaya, O.Y., Groznova, E.O., Kovalenker, V.A. et al. Mineralogy and formation conditions of ores in the Bereznyakovskoe ore field, the Southern Urals, Russia. Geol. Ore Deposits 51, 371–397 (2009). https://doi.org/10.1134/S1075701509050031

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