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Synthesis of Multidentate Chalcogen-Containing Ligands Based on Bis(2-bromoethyl) Sulfide

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Abstract

Derivatives of bis(2-bromoethyl) sulfide of the general formula (RSCH2CH2)2S, where R = Me, Et, Pr, i-Pr, Bu, i-Bu, t-Bu, C6H13, Cy, Ph, and Bn, were synthesized and characterized by IR and 1H and 13C NMR spectra. The synthesized compounds are potential electron-donating multidentate ligands that are promising for the preparation of coordination compounds and as components of catalytic systems for catalytic transformations of ethylene.

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ACKNOWLEDGMENTS

This study was performed using the facilities of the joint analytical center at the Irkutsk State University (http://ckp-rf.ru/ckp/3264/) and Baikal joint analytical canter (Siberian Branch, Russian Academy of Sciences). The authors thank senior researcher M.V. Bykov (Research Institute of Petrochemical and Coal Chemical Synthesis, Irkutsk State University) for recording the IR spectra.

Funding

This work was supported by the Government Assignment for Scientific Research from the Ministry of Science and Higher Education of the Russian Federation (agreement no. 075-03-2020-176/3; project code in Parus 8: FZZE-2020-0022).

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Authors and Affiliations

  1. Irkutsk State University, 664003, Irkutsk, Russia

    V. A. Bezborodov, I. A. Babenko, G. V. Ratovskii & A. I. Vilms

  2. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 664033, Irkutsk, Russia

    I. A. Ushakov

Authors
  1. V. A. Bezborodov
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  2. I. A. Babenko
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  3. G. V. Ratovskii
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  4. I. A. Ushakov
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  5. A. I. Vilms
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Corresponding author

Correspondence to I. A. Babenko.

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The authors declare the absence of conflict of interest.

Additional information

Translated from Zhurnal Organicheskoi Khimii, 2021, Vol. 57, No. 10, pp. 1482–1489 https://doi.org/10.31857/S0514749221100153.

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Bezborodov, V.A., Babenko, I.A., Ratovskii, G.V. et al. Synthesis of Multidentate Chalcogen-Containing Ligands Based on Bis(2-bromoethyl) Sulfide. Russ J Org Chem 57, 1662–1667 (2021). https://doi.org/10.1134/S1070428021100158

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