Abstract
5-Phenyl-4-ethoxycarbonyl-1H-pyrrole-2,3-diones react with acetonitriles and dimedone to form ethyl 2-amino-7,7-dimethyl-2′,5-dioxo-5′-phenyl-1′,2′,5,6,7,8-hexahydrospiro[chromene-4,3′-pyrrole]-4′-carboxylates. The crystal and molecular structure of ethyl 2-amino-1′-benzyl-7,7-dimethyl-2′,5-dioxo-5′-phenyl-3-cyano-1′,2′,5,6,7,8-hexahydrospiro[chromene-4,3′-pyrrole]-4′-carboxylate was proved by XRD analysis.
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Original Russian Text © M.V. Dmitriev, P.S. Silaichev, Z.G. Aliev, A.N. Maslivets, 2011, published in Zhurnal Organicheskoi Khimii, 2011, Vol. 47, No. 8, pp. 1147–1150.
For Communication LXXVIII, see [1].
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Dmitriev, M.V., Silaichev, P.S., Aliev, Z.G. et al. Five-membered 2,3-dioxoheterocycles: LXXIX. Three-component condensation of 1H-pyrrol-2,3-diones with acetonitriles and dimedone. Crystal and molecular structure of substituted spiro[chromene-4,3′-pyrrole]. Russ J Org Chem 47, 1165–1168 (2011). https://doi.org/10.1134/S1070428011080082
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DOI: https://doi.org/10.1134/S1070428011080082