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Photoaddition of Dicarboxylic Acid Esters, Derivatives of Heterocyclic Compounds and Acenaphthene to Fullerene C60

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Abstract

New possibilities of the photochemical addition to fullerene С60 were demonstrated. Monosubstituted 1,9-dihydrofullerenes were obtained by irradiation of С60 in the presence of homologues of thiophene, pyridine, and naphthalene as well as esters of glutaric, phthalic, succinic, adipic, pyridinedicarboxylic acids and N-alkyllactam. The HC60 moiety is bound to the hydrocarbon part of the organic fragment. The product of the methyl glutarate addition was reduced by bis(arene)chromium to give a new ion-radical salt.

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Funding

This work was carried out within the state assignment of the Ministry of Science and Higher Education of the Russian Federation using the equipment of the Center for Collective Use “Analytical Center of the IOMC RAS” with the financial support of the grant “Ensuring the development of the material and technical infrastructure of the centers for collective use of scientific equipment” (unique identifier RF-2296.61321X0017, agreement number 075-15-2021-670).

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Authors and Affiliations

  1. G.A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences, 603950, Nizhny Novgorod, Russia

    G. V. Markin, E. A. Kozlova, M. A. Lopatin, V. A. Kuropatov, A. A. Belikov & S. Yu. Ketkov

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  1. G. V. Markin
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  2. E. A. Kozlova
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  3. M. A. Lopatin
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  4. V. A. Kuropatov
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  5. A. A. Belikov
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  6. S. Yu. Ketkov
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Correspondence to G. V. Markin.

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To the 35th Anniversary of the founding of the G.A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences

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Markin, G.V., Kozlova, E.A., Lopatin, M.A. et al. Photoaddition of Dicarboxylic Acid Esters, Derivatives of Heterocyclic Compounds and Acenaphthene to Fullerene C60. Russ J Gen Chem 93 (Suppl 3), S663–S671 (2023). https://doi.org/10.1134/S1070363223160041

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  • DOI: https://doi.org/10.1134/S1070363223160041

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