Abstract
It was established by the method HPLC-MS with electrospray ionization that in solutions of fullerenes C60 and C70 in some essential oils a chemical reaction occurred leading to adducts of fullerenes with unsaturated terpenes. In the course of time the quantity of the adduct in solution increased and a component originating from addition of two molecules of terpene to a molecule of fullerene is formed. This can be the reason of abnormally high solubility of light fullerenes in mixtures of terpene hydrocarbons.
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Original Russian Text © L.A. Konopelko, A.N. Krilov, E.M. Lopushanskaya, O.G. Popov, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 2, pp. 211–214.
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Konopelko, L.A., Krilov, A.N., Lopushanskaya, E.M. et al. Adducts formation at fullerenes C60 and C70 dissolution in essential oils. Russ J Gen Chem 84, 205–208 (2014). https://doi.org/10.1134/S1070363214020078
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DOI: https://doi.org/10.1134/S1070363214020078