Abstract
N,N-Bis(silatranylmethyl)methylamine reacts with trichlorosilane to form the amine hydrochloride and perchloropolysilane, the product of polymerization of dichlorosilylene. In the presence of 1,3-butadiene the main products of the reaction are the amine hydrochloride and 1,1-dichlorosilacyclopentene-3, the product of 1,4-addition of dichlorosilylene to 1,3-butadiene.
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Original Russian Text © N.F. Lazareva, I.M. Lazarev, 2011, published in Zhurnal Obshchei Khimii, 2011, Vol. 81, No. 10, pp. 1653–1655.
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Lazareva, N.F., Lazarev, I.M. Reaction of N-methyl-N,N-bis(silatranylmethyl)amine with trichlorosilane. Russ J Gen Chem 81, 2106–2108 (2011). https://doi.org/10.1134/S1070363211100112
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DOI: https://doi.org/10.1134/S1070363211100112