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Complexes of 1-(4-Methoxyphenyl)-1,4-Dihydro-5H-Tetrazole-5-Thione and 1-(2-Methoxyphenyl)-1,4-Dihydro-5H-Tetrazole-5-Thione with Cadmium Chloride: Synthesis and Molecular and Crystal Structures

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Abstract

New complex compounds [Cd(μ-L1)2]n (I), [Cd(μ-L2)(μ-Cl)(μ-DMSO)]n (III), and [Cd2(μ-L2)(μ-Cl)3(μ-DMSO)DMSO/EtOH]n (IV) are synthesized by the reactions of 1-(4-methoxyphenyl)-1,4-dihydro-5H-tetrazole-5-thione (HL1) and 1-(2-methoxyphenyl)-1,4-dihydro-5H-tetrazole-5-thione (HL2) with cadmium chloride. The molecular and crystal structures of the complexes are determined by X-ray structure analysis (CIF files CCDC nos. 1993455 (I), 1869249 (III), and 1993497 (IV)). Complexes I, III, and IV have uniform polymeric structures. The О···Н, Cl···H, and C···S contacts are observed between 1D polymeric chains in the crystal cells of complexes I, III, and IV. Complexes III and IV contain DMSO molecules. Under other equivalent conditions, the reaction of HL1 or HL2 with cadmium chloride in ethanol affords complex I or II of different compositions. Complex II contains the chlorine atom as found by scanning electron microscopy, whereas no chlorine is observed in complex I according to the X-ray structure analysis data.

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ACKNOWLEDGMENTS

This work was carried out using equipment of the Center for Collective Use “Novel Materials and Resource Saving Technologies” (Lobachevskii State University, Nizhny Novgorod, Russia).

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Authors and Affiliations

  1. Baku State University, Baku, Azerbaijan

    R. K. Askerov & A. M. Magerramov

  2. Alekseev State Technical University, Nizhny Novgorod, Russia

    V. K. Osmanov, O. N. Kovaleva & A. V. Borisov

  3. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603600, Nizhny Novgorod, Russia

    E. V. Baranov & G. K. Fukin

  4. Lobachevskii State University, Nizhny Novgorod, Russia

    D. G. Fukina & A. V. Boryakov

Authors
  1. R. K. Askerov
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  2. V. K. Osmanov
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  3. O. N. Kovaleva
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  4. E. V. Baranov
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  5. G. K. Fukin
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  7. A. V. Boryakov
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  8. A. M. Magerramov
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  9. A. V. Borisov
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Correspondence to R. K. Askerov.

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Translated by E. Yablonskaya

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Askerov, R.K., Osmanov, V.K., Kovaleva, O.N. et al. Complexes of 1-(4-Methoxyphenyl)-1,4-Dihydro-5H-Tetrazole-5-Thione and 1-(2-Methoxyphenyl)-1,4-Dihydro-5H-Tetrazole-5-Thione with Cadmium Chloride: Synthesis and Molecular and Crystal Structures. Russ J Coord Chem 47, 741–750 (2021). https://doi.org/10.1134/S1070328421110014

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