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Synthesis and crystal structure of the new complex bis(4,4,10,10-tetramethyl-1,3,7,9-tetraazospiro[5.5]undecane-2,8-dione-O)diaquatris(nitrato-O,O′)cerium(III)

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Abstract

A mononuclear biligand complex of cerium(III) nitrate with bicyclic bisurea (4,4,10,10-tetramethyl-1,3,7,9-tetraazospiro[5.5]undecane-2,8-dione or spirocarbone (Sk)), Ce(C11H20N4O2)2(H2O)2(NO3)3 (I), is synthesized. Its structure is determined by X-ray diffraction analysis (CIF file CCDC 985759). The crystals are monoclinic: space group P21/c, a = 11.1935(5), b = 13.0139(5), c = 24.1857(10) Å, β = 101.146(4)°, V = 3456.7(3) Å3, ρcalcd = 1.619 g/cm3, Ζ = 4. The structure is molecular. The cerium(III) cation is coordinated by two oxygen atoms of two molecules of the organic ligand, two O(H2O) atoms, and six O atoms of three bidentate nitrate anions. The coordination number of the cerium(III) atom is ten, and the coordination polyhedron is an irregular ten-vertex polyhedron. The crystal is a non-merohedral twin, whose components are turned by 180° along the x axis, and the relative weights of the components are 0.82 : 0.18.

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Authors and Affiliations

  1. Krym Federal University, ul. Yaltinskaya 4, Simferopol, Crimea, Russia

    E. E. Netreba

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  1. E. E. Netreba
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Original Russian Text © E.E. Netreba, 2015, published in Koordinatsionnaya Khimiya, 2015, Vol. 41, No. 11, pp. 693–699.

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Netreba, E.E. Synthesis and crystal structure of the new complex bis(4,4,10,10-tetramethyl-1,3,7,9-tetraazospiro[5.5]undecane-2,8-dione-O)diaquatris(nitrato-O,O′)cerium(III). Russ J Coord Chem 41, 765–771 (2015). https://doi.org/10.1134/S1070328415110044

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