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Framework polymers based on octahedral chalcocyanide cluster [Re6Q8(CN)6]4−/3− anions (Q = Se, Te) and [Nd(Bipy)n]3+ Complexes (n = 1, 2)

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Abstract

Interaction of salts of the cluster anions {Re [Re6Q8(CN)6]4−/3− (Q = Se, Te) with Nd salts in the presence of 2,2′-bipyridyl (Bipy) ligand brings about new coordination polymers: Pr n4 N[{Nd(Bipy)(H2O)4} {Re6Se8(CN)6}] · 2H2O (I) (space group C2/c, a = 18.2918(16) Å, b = 14.9972(13) Å, c = 37.513(3) Å, β = 102.046(4)°, V = 10064.2(15) Å3, Z = 8), [{Nd(Bipy)2(H2O)} {Re6Se8(CN)6}] (II) (space group C2/c, a = 15.8668(3) Å, b = 13.5403(3) Å, c = 20.5189(4) Å, β = 110.135(1)°, V = 4138.89(15) Å3, Z = 4), and [{Nd(Bipy)(EtOH)(H2O)4}{Re6Te8(CN)6}] · EtOH (III) (space group \(P\bar 1\), a = 9.4733(6) Å, b = 12.5326(8) Å, c = 17.2374(11) Å, α = 96.561(2)°, β = 90.310(2)°, γ = 94.876(2)°, V = 4138.89(15) Å3, Z = 4). The compounds synthesized are characterized by single-crystal X-ray diffraction and IR methods. Compounds I and III have layered (2D) structures, compound II is a framework (3D) polymer.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    M. S. Tarasenko, N. G. Naumov, D. Yu. Naumov, N. V. Kuratieva & V. E. Fedorov

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  1. M. S. Tarasenko
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  2. N. G. Naumov
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  3. D. Yu. Naumov
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  4. N. V. Kuratieva
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  5. V. E. Fedorov
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Original Russian Text © M.S. Tarasenko, N.G. Naumov, D.Yu. Naumov, N.V. Kuratieva, V.E. Fedorov, 2006, published in Koordinatsionnaya Khimiya, 2006, Vol. 32, No. 7, pp. 517–526.

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Tarasenko, M.S., Naumov, N.G., Naumov, D.Y. et al. Framework polymers based on octahedral chalcocyanide cluster [Re6Q8(CN)6]4−/3− anions (Q = Se, Te) and [Nd(Bipy)n]3+ Complexes (n = 1, 2). Russ J Coord Chem 32, 494–503 (2006). https://doi.org/10.1134/S1070328406070062

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  • DOI: https://doi.org/10.1134/S1070328406070062

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