Abstract
The SiO2/ZnO nanocomposite with a core-shell structure for photocatalysis from water-soluble zinc salts and sodium silicate was synthesized using the hydrothermal-microwave method. The physicochemical properties of the synthesized SiO2/ZnO were studied and its photocatalytic activity was tested. The band gaps of the heat-treated composite \(E_{{\text{g}}}^{{{\text{dir}}}}\) and \(E_{{\text{g}}}^{{{\text{indir}}}}\) are 3.35 and 3.32 eV, respectively. The photocatalytic activity of the resulting SiO2/ZnO was determined by the decomposition reaction of methylene blue under UV irradiation. The conversion of methylene blue was determined by optical method. The resulting SiO2/ZnO has high photocatalytic activity. The conducted studies showed the effectiveness of microwave synthesis of SiO2/ZnO with a core-shell structure in comparison with traditional methods.
REFERENCES
Artemyev, Yu.M. and Ryabchuk, V.K., Vvedeniye v geterogennyy fotokataliz (Introduction to heterogeneous photocatalysis). St. Petersburg, St. Petersburg State University, 1999
Kulakova, I.I. and Lisichkin, G.V., Katalicheskaya khimiya. Chast’ 1. Osnovy kataliza (Catalytic chemistry. Part 1. Basics of catalysis). Moscow, MGU, 2014.
Messih, M.F.A., Shalan, A.E., Sanad, M.F., and Ahmed, A., J. Materials Science: Materials in Electronics, 2019, vol. 30, p. 14291.
Lee, K.M., Lai, C.W., Ngai, K.S., and Juan, J.C., Water Research., 2016, vol. 88, p. 428.
Di Mauro, A., Fragalà, M.E., Privitera, V., and Impellizzeri, G., Materials Science in Semiconductor Processing, 2017, vol. 69, p. 44.
Shidpour, R., Simchi, A., Ghanbari, F., and Vossoughi, M., Applied Catalysis A: General, 2014, vol. 472, p. 198.
Ulyankina, A.A., Leontyev, I.N., and Smirnova, N.V., Elektronnyy nauchnyy zhurnal “Inzhenernyy vestnik Dona” (Electronic scientific journal “Engineering Bulletin of the Don”), 2017, no. 4, p. 1 [in Russian].
Zhang, W. and Yanagisawa, K., Chemistry of Materials, 2007, vol. 19, p. 2329.
Ali, A.M., Ismail, A.A., Najmye, R., and Al-Hajryc, A., J. Photochemistry and Photobiology A: Chemistry, 2014, vol. 275, p. 37.
Bozhinova, A.S., Kaneva, N.V., Kononova, I.E., Nalimova, S.S., Suleiman, Sh.A., Papazova, K.I., Dimitrov, D.Ts., Moshnikov, V.A., and Terukov, E.I., Fizika i tekhni-ka poluprovodnikov (Physics and technology of semiconductors,) 2013, vol. 47, p. 1662.
Baghramyan, V.V., Sargsyan, A.A., Gurgenyan, N.V., Sargsyan, A.A., Knyazyan, N.B., Arutyunyan, V.V., Aleksanyan, E.M., Grigoryan, N.E., and Sahaakyan, A.A., Theoretic. Found. Chem. Engineering, 2018, vol. 49, p. 897.
Baghramyan, V.V., Sargsyan, A.A., Knyazyan, N.B., Harutyunyan, V.V., Badalyan, A.H., Grigoryan, N.E., Aprahamianc, A., and Manukyan, K.V., Ceramics International., 2020, vol. 46, p. 4992.
Brittany, H., Microwave Synthesis, CEM publishing, 2002.
Mandal, A.K. and Sen, R., Materials and Manufacturing Processes, 2017, vol. 32, p. 1.
Sargsyan, A.A., Bagramyan, V.V., Knyazyan, N.B., Ovsepyan, R.K., Agamalyan, N.R., and Badalyan, G.R., J. Contemp. Phys., 2020, vol. 55, p. 360.
Bagramyan, V.V., Sargsyan, A.A., Knyazyan, N.B., Kazaryan, A.A., and Grigoryan, T.V., Khimicheskiy zhurnal Armenii (Chemical Journal of Armenia), 2021, vol. 74, p. 191.
Bagramyan, V.V., Sargsyan, A.A., Knyazyan, N.B., Kazaryan, A.A., and Grigoryan, T.V., Khimicheskiy zhurnal Armenii (Chemical Journal of Armenia), 2021, vol. 74, p. 191.
Bahadur, N.M., Chowdhury, F., Obaidullah, Md., Hossain, Md.Sh., Rashid, R., Akter, Y., Furusawa, T., Sato, M., and Suzuki, N., J. Nanomaterials, 2019, art. ID 6368789.
Jiang, T., Wang, X., Zhou, J., Chen, D., and Zhao, Z., Nanoscale, 2016, vol. 8, p. 4908.
Weis, F., Seipenbsch, M., and Kasper, G., Materials, 2015, vol. 8, p. 966.
Zheng, J., Liu, Z.Q., Zhao, X.S., Liu, M., Liu, X., and Chu, W., Nanotechnology, 2012, vol. 23, p. 165601.
Bershtein, A., Gun’ko, V.M., Egorova, L.M., Guzenko, N.V., Pakhlov, E.M., Ryzhov, V.A., and Zarko, V.I., Langmuir, 2010, vol. 26, p. 10968.
Bagramyan, V.V. and Sargsyan, A.A., Khimicheskiy zhurnal Armenii (Chemical Journal of Armenia), 2020, vol. 73, p. 176 [in Russian].
Burdina, A.S., Gagarina, K.I., Gabov, A.A., and Mironov, A.A., Prikladnaya fotonika (Applied Photonics), 2018, vol. 5, p. 22.
Duran, A., Sema, C., Fornes, V., et al., J. Non-Crystalline Solids, 1986, vol. 82, p. 69.
Xia, H.L. and Tang, F.Q., J. Phys Chem. B, 2003, vol. 107, p. 9175.
Galedari, N.A., Rahmani, M., and Tashihi, M., Environ. Sci. Pollution Res., 2017, vol. 24, p. 12655.
Cenens, J. and Schoonheydt, R.A., Clays and Clay Minerals, 1988, vol. 36, p. 214.
Cristiano, E., Hu, Y.-J., Siegfried, M., Kaplan, D., and Nitsch, H., Clays and Clay Mineral, 2011, vol. 5, p. 107.
Tan, W.-F., Lu, S.-J., Liu, F., Feng, X.-H., He, J.-Z., and Koopal, L.K., Soil Science, 2008, vol. 173, p. 277.
Funding
The research was carried out with the financial support of the Science Committee of the Ministry of Education, Science, Culture and Sports of the Republic of Armenia within the framework of Scientific Project No. 21T-1D146 “Microwave synthesis of composites with photocatalytic properties”.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors of this work declare that they have no conflicts of interest.
Additional information
Translated by V. Musakhanyan
Publisher’s Note.
Pleiades Publishing remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
About this article
Cite this article
Sargsyan, A.A., Mnatsakanyan, R.A., Grigoryan, T.V. et al. Microwave–Assisted Synthesis of SiO2/ZnO Photocatalyst with Core-Shell Structure. J. Contemp. Phys. 58, 397–404 (2023). https://doi.org/10.1134/S1068337223040163
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1068337223040163