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Molecular and crystal structure of tris-(2-hydroxyethyl)ammonium 4-chlorophenoxy acetate

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Abstract

Tris-(2-hydroxyethyl)ammonium 4-chlorophenoxy acetate has been synthesized and characterized by 1H NMR spectra. The molecular structure of this compound has been established by single-crystal X-ray diffractometry (a = 7.5298(23) Å, b = 22.8112(46) Å, c = 10.0921(16) Å, β = 111.42(2)°, V = 1613.7(7) Å3, sp. gr. P21/c, d calcd = 1.382 g/cm3). In a cation, the hydrogen atom, in the presence of a nitrogen atom, forms three intramolecular hydrogen bonds with the O atoms of hydroxyl groups [2.29(3)–2.31(3) Å]. At the same time, all three cation hydroxyl groups are involved in the formation of three intermolecular H bonds with oxygen atoms of the carboxyl anion group [H-O = 1.81(5)−2.06(4) Å].

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References

  1. M. G. Voronkov and V. P. Baryshok, Vestn. Ross. Akad. Nauk, 80(11), 985 (2010).

    Google Scholar 

  2. G. L. Starova, O. V. Frank-Kamenetskaya, V. S. Fundamenskii, et al., Dokl. Akad. Nauk SSSR, 260(4), 888 (1981).

    Google Scholar 

  3. S. V. Loginov, V. D. Sheludyakov, A. M. Abramkin, et al., Khim. Prom. Segodnya, No. 4, 25 (2011).

  4. CAD4 Software (Enraf-Nonius, Delft, The Netherlands, 1994).

  5. K. Harms and S. Wocaldo, XCAD4 (University of Marburg, Marburg, 1995).

    Google Scholar 

  6. G. M. Sheldrick, Acta Crystallogr. A 64, 112 (2008).

    Article  ADS  Google Scholar 

  7. N. Walker and D. Stuart, Acta Crystallogr. A 39, 158 (1983).

    Article  Google Scholar 

  8. L. J. Farrugia, J. Appl. Crystallogr. 30, 565 (1997).

    Article  Google Scholar 

  9. F. R. Allen, Acta Crystallogr. B. 58, 380 (2002).

    Article  Google Scholar 

  10. L. J. Farrugia, J. Appl. Crystallogr. 32, 837 (1999).

    Article  Google Scholar 

Download references

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Correspondence to V. B. Rybakov.

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Original Russian Text © S.V. Loginov, A.M. Abramkin, V.B. Rybakov, V.D. Sheludyakov, P.A. Storozhenko, 2012, published in Kristallografiya, 2012, Vol. 57, No. 4, pp. 590–592.

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Loginov, S.V., Abramkin, A.M., Rybakov, V.B. et al. Molecular and crystal structure of tris-(2-hydroxyethyl)ammonium 4-chlorophenoxy acetate. Crystallogr. Rep. 57, 521–523 (2012). https://doi.org/10.1134/S1063774512040141

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  • DOI: https://doi.org/10.1134/S1063774512040141

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