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Electrochemical Synthesis of Hybrid Materials Based on Polyelectrolyte Complexes of Chitosan and Their Physicochemical Properties

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Abstract

The morphology, structure, and elemental composition of hybrid materials based on polyelectrolyte complexes of chitosan with nickel and cobalt oxides formed on the surface of stainless steel are studied by using asymmetric alternating current. The X-ray phase analysis has shown that cobalt hydroxyisocyanate is the main phase of these hybrid materials. These hybrid materials are shown to be promising as the electrodes in supercapacitors with alkaline electrolyte, their specific capacitance reaching 479 F g‒1 at the current density of 1 A g–1. The antimicrobial activity of hybrid materials with respect to gram-positive (S. aureus) and gram-negative (E. coli) bacteria is revealed. The corrosion-protective properties of the hybrid materials are studied in 3.5 mass % NaCl solution. They are shown to shift the corrosion potential in the positive region as compared with unprotected steel.

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ACKNOWLEDGMENTS

We are grateful to M.A. Khimich and I.Yu. Litovchenko for their help with interpretation of the results of XRD studies of hybrid materials.

Funding

This study was supported by Student’s Startup of the Foundation for Promotion of Small Companies in the Scientific and Technological Sphere (grant no. 159GSSS15-L/78896).

Author information

Authors and Affiliations

  1. Platov South-Russian State Polytechnic University, Novocherkassk, Russia

    A. V. Khramenkova & D. N. Izvarina

  2. Don State Technical University, Rostov-on-Don, Russia

    V. I. Mishurov

  3. Ivanovo State Medical Academy, Ivanovo, Russia

    A. A. Shershakova, M. A. Kirilenko & O. Yu. Kuznetsov

Authors
  1. A. V. Khramenkova
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  2. D. N. Izvarina
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  3. V. I. Mishurov
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  4. A. A. Shershakova
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  5. M. A. Kirilenko
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  6. O. Yu. Kuznetsov
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Corresponding authors

Correspondence to A. V. Khramenkova or D. N. Izvarina.

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The authors declare that they have no conflict of interest.

Additional information

Translated by T. Safonova

Delivered at the 20th All-Russian Meeting “Electrochemistry of Organic Compounds” (EKhOS-2022), Novocherkassk, October 18–22, 2022.

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Khramenkova, A.V., Izvarina, D.N., Mishurov, V.I. et al. Electrochemical Synthesis of Hybrid Materials Based on Polyelectrolyte Complexes of Chitosan and Their Physicochemical Properties. Russ J Electrochem 59, 887–895 (2023). https://doi.org/10.1134/S1023193523110083

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  • DOI: https://doi.org/10.1134/S1023193523110083

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