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Dielectric Relaxation of Nanocomposites Based on Poly(phenylene oxide) and Endometallofullerene

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Abstract

The molecular mobility of poly(phenylene oxide) nanocomposites with endometallofullerene at a concentration of 0.1, 0.5, and 1.0 wt % is studied by dielectric spectroscopy. Two processes of dipole polarization relaxation in the glassy state (β-process) and in the rubbery state (α-process) are found. It is shown that the molecular mobility of the β-process related to the presence of a nanoadditive does not change with concentration. Molecular mobility in the region of the α-process, which is associated with segmental mobility, shows a downward trend.

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, 199004, St. Petersburg, Russia

    N. A. Nikonorova & G. A. Polotskaya

  2. Russian State Pedagogical University, 191186, St. Petersburg, Russia

    A. A. Kononov & R. A. Castro

Authors
  1. N. A. Nikonorova
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  2. A. A. Kononov
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  3. G. A. Polotskaya
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  4. R. A. Castro
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Correspondence to N. A. Nikonorova.

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Nikonorova, N.A., Kononov, A.A., Polotskaya, G.A. et al. Dielectric Relaxation of Nanocomposites Based on Poly(phenylene oxide) and Endometallofullerene. Polym. Sci. Ser. A 62, 116–122 (2020). https://doi.org/10.1134/S0965545X20020029

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  • DOI: https://doi.org/10.1134/S0965545X20020029

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