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Microporous structure of highly permeable additive silicon-containing polytricyclononenes

  • Polymeric Membranes
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Abstract

The porosity of a number of additive silicon-containing polytricyclononenes from the class of highly permeable polymers has been systematically studied for the first time by the method of low-temperature nitrogen adsorption/desorption. It has been shown that these polymers have a large specific surface area (390−790 m2/g) and are microporous. Dominant pore size ranges from 7 to 10 Å depending on the number of Me3Si groups in a monomer unit and their relative position.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, 119991, Russia

    P. P. Chapala & M. V. Bermeshev

  2. Mendeleev University of Chemical Technology of Russia, Miusskaya pl. 9, Moscow, 125047, Russia

    N. N. Gavrilova

Authors
  1. P. P. Chapala
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  2. M. V. Bermeshev
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  3. N. N. Gavrilova
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Corresponding author

Correspondence to M. V. Bermeshev.

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Original Russian Text © P.P. Chapala, M.V. Bermeshev, N.N. Gavrilova, 2017, published in Vysokomolekulyarnye Soedineniya, Seriya A, 2017, Vol. 59, No. 1, pp. 95–100.

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Chapala, P.P., Bermeshev, M.V. & Gavrilova, N.N. Microporous structure of highly permeable additive silicon-containing polytricyclononenes. Polym. Sci. Ser. A 59, 143–148 (2017). https://doi.org/10.1134/S0965545X17010035

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  • DOI: https://doi.org/10.1134/S0965545X17010035

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