Abstract
Advantages and comparison of thermal analysis (TA) and Knudsen effusion mass spectrometry (KEMS) were discussed for the investigation of high temperature behavior of oxide systems such as ceramics and glass-forming melts. This brief overview proposes filling the gap by considering various approaches of interaction between the TA and KEMS data. The reliability of experimental data found using both methods is critically analyzed for thermodynamic values of the lanthanoid hafnates obtained by DSC and KEMS and mass losses of the samples in the Bi2O3–P2O5–SiO2 system found by thermogravimetry and KEMS. Recent achievements in experimental installations for these methods were also noted.
Similar content being viewed by others
REFERENCES
T. Ozawa, Thermochim. Acta 355, 35 (2000). https://doi.org/10.1016/S0040-6031(00)00435-4
F. Rouquerol, J. Rouquerol, and P. Llewellyn, in Developments in Clay Science (Elsevier, Amsterdam, 2013), Vol. 5, Chap. 2.12, p. 361. https://doi.org/10.1016/B978-0-08-098259-5.00014-7
J. Šesták, P. Holba, and K. S. Gavrichev, J. Therm. Anal. Calorim. 119, 779 (2015). https://doi.org/10.1007/s10973-014-4151-2
P. Šulcová, J. Šesták, A. Menyhárd, and G. Liptay, J. Therm. Anal. Calorim. 120, 239 (2015). https://doi.org/10.1007/s10973-015-4550-z
K. S. Gavrichev, Russ. J. Inorg. Chem. 65, 695 (2020). https://doi.org/10.1134/S0036023620050095
A. Navrotsky, J. Am. Ceram. Soc. 97, 3349 (2014). https://doi.org/10.1111/jace.13278
K. S. Gavrichev, Inorg. Mater. 39 (Suppl. 2), S89 (2003). https://doi.org/10.1023/B:INMA.0000008888.25890.51
V. B. Lazarev, K. S. Gavrichev, and J. H. Greenberg, Pure Appl. Chem. 63, 1341 (1991). https://doi.org/10.1351/pac199163101341
B. A. Rusanov, V. E. Sidorov, P. Svec, P. Svec, and D. Janickovic, Russ. J. Inorg. Chem. 65, 663 (2020). https://doi.org/10.1134/S0036023620050198
M. A. Ryumin, Z. V. Dobrokhotova, A. L. Emelina, M. A. Bukov, N. V. Gogoleva, K. S. Gavrichev, E. N. Zorina-Tikhonova, L. I. Demina, M. A. Kiskin, A. A. Sidorov, I. L. Eremenko, and V. M. Novotortsev, Polyhedron 87, 28 (2015). https://doi.org/10.1016/j.poly.2014.10.031
C. Schick, Anal. Bioanal. Chem. 395, 1589 (2009). https://doi.org/10.1007/s00216-009-3169-y
E. Gómez, N. Calvar, Á. Domínguez, and E. A. Macedo, Fluid Phase Equilib. 470, 51 (2018). https://doi.org/10.1016/j.fluid.2018.04.003
S. V. Ushakov and A. Navrotsky, J. Am. Ceram. Soc. 95, 1463 (2012). https://doi.org/10.1111/j.1551-2916.2012.05102.x
D. M. Price, Thermochim. Acta 367–368, 253 (2001). https://doi.org/10.1016/S0040-6031(00)00676-6
D. M. Price, Thermochim. Acta 622, 44 (2015). https://doi.org/10.1016/j.tca.2015.04.030
J. R. Opfermann, E. Kaisersberger, and H. J. Flammersheim, Thermochim. Acta 391, 119 (2002). https://doi.org/10.1016/S0040-6031(02)00169-7
G. A. Semenov, E. N. Nikolaev, and K. E. Frantseva, Application of Mass Spectrometry in Inorganic Chemistry (Khimiya, Leningrad, 1976) [in Russian].
V. L. Stolyarova and G. A. Semenov, Mass Spectrometric Study of the Vaporization of Oxide Systems (Wiley, Chichester, 1994).
V. L. Stolyarova, CALPHAD 64, 258 (2019). https://doi.org/10.1016/J.CALPHAD.2018.12.013
E. N. Kablov, Y. I. Folomeikin, V. L. Stolyarova, and S. I. Lopatin, Dokl. Phys. Chem. 463, 150 (2015). https://doi.org/10.1134/S0012501615070039
V. L. Stolyarova, Russ. Chem. Rev. 85, 60 (2016). https://doi.org/10.1070/RCR4549
M. M. Shul’ts, I. Y. Archakov, M. V. Sazonova, and V. L. Stolyarova, Sov. J. Glass Phys. Chem. 16, 158 (1991).
V. L. Stolyarova, I. Y. Archakov, A. N. Gordeev, et al., Rapid Commun. Mass Spectrom. 7, 127 (1993). https://doi.org/10.1002/rcm.1290070203
V. G. Sevastyanov, E. P. Simonenko, N. P. Simonenko, et al., Mater. Chem. Phys. 153, 78 (2015). https://doi.org/10.1016/j.matchemphys.2014.12.037
V. A. Vorozhtcov, V. L. Stolyarova, M. V. Chislov, et al., J. Mater. Res. 34, 3326 (2019). https://doi.org/10.1557/jmr.2019.206
V. L. Stolyarova, V. A. Vorozhtcov, S. I. Lopatin, and V. L. Ugolkov, Thermochim. Acta 685, 178531 (2020). https://doi.org/10.1016/j.tca.2020.178531
T. Meisel, K. Seybold, and D. Schultze, CRC Crit. Rev. Anal. Chem. 12, 267 (1981). https://doi.org/10.1080/10408348108542748
P. Brož and F. Zelenka, Int. J. Mass Spectrom. 383, 13 (2015). https://doi.org/10.1016/j.ijms.2015.04.002
P. Brož, F. Zelenka, J. Sopoušek, et al., CALPHAD 65, 86 (2019). https://doi.org/10.1016/j.calphad.2019.02.007
N. Jacobson, D. Kobertz, and D. Sergeev, CALPHAD 65, 111 (2019). https://doi.org/10.1016/j.calphad.2019.01.004
P. Brož, M. Hejduková, V. Vykoukal, et al., CALPHAD 64, 334 (2019). https://doi.org/10.1016/j.calphad.2019.01.013
P. Brož, F. Zelenka, Z. Kohoutek, et al., CALPHAD 65, 1 (2019). https://doi.org/10.1016/j.calphad.2019.01.012
Knudsen Effusion Mass Spectrometry Electronic Resource, Mass Spectrometry Instruments Ltd. https://www.massint.co.uk/kems/knudsen-effusion-ms.php. Accessed April 14, 2020.
J. Y. Colle and F. Capone, Rev. Sci. Instrum. 79, 055105 (2008). https://doi.org/10.1063/1.2918135
V. A. Vorozhtcov, V. L. Stolyarova, S. I. Lopatin, et al., Rapid Commun. Mass Spectrom. 31, 111 (2017). https://doi.org/10.1002/rcm.7764
R. J. M. Konings, O. Beneš, A. Kovács, et al., J. Phys. Chem. Ref. Data 43, 013101 (2014). https://doi.org/10.1063/1.4825256
L. V. Gurvich, I. V. Veitz, V. A. Medvedev, et al., Thermodynamic Properties of Individual Substances (Nauka, Moscow, 1982), Vol. 4, Part 2 [in Russian].
R. Babu and K. Nagarajan, J. Alloys Compd. 265, 137 (1998). https://doi.org/10.1016/S0925-8388(97)00430-1
A. R. Kopan’, M. P. Gorbachuk, S. M. Lakiza, and Y. S. Tishchenko, Powder Metall. Met. Ceram. 54, 696 (2016). https://doi.org/10.1007/s11106-016-9764-5
F. A. López-Cota, N. M. Cepeda-Sánchez, J. A. Díaz-Guillén, et al., J. Am. Ceram. Soc. 100, 1994 (2017). https://doi.org/10.1111/jace.14712
S. V. Ushakov, A. Navrotsky, J. A. Tangeman, and K. B. Helean, J. Am. Ceram. Soc. 90, 1171 (2007). https://doi.org/10.1111/j.1551-2916.2007.01592.x
V. A. Vorozhtcov, V. L. Stolyarova, S. I. Lopatin, et al., J. Alloys Compd. 735, 2348 (2018). https://doi.org/10.1016/J.JALLCOM.2017.11.319
M. Knudsen, Ann. Phys. 336, 205 (1909). https://doi.org/10.1002/andp.19093360110
M. Knudsen, Ann. Phys. 29, 999 (1909).
M. Knudsen, Ann. Phys. 334, 179 (1909). https://doi.org/10.1002/andp.19093340614
E. K. Kazenas and Y. V. Tsvetkov, Thermodynamics of Evaporation of Oxides (LKI, Moscow, 2008) [in Russian].
V. L. Stolyarova, V. A. Vorozhtcov, and S. I. Lopatin, in Proceedings of the 22nd International Conference on Chemical Thermodynanics in Russia (Petropolis PH, St. Petersburg, 2019), p. 40.
L. N. Sidorov and V. B. Shol’ts, Int. J. Mass Spectrom. Ion Phys. 8, 437 (1972). https://doi.org/10.1016/0020-7381(72)80014-7
L. N. Sidorov and P. A. Akishin, Dokl. Akad. Nauk SSSR 151, 136 (1963).
Funding
This study was funded by the Russian Foundation for Basic Research (grant nos. 13-03-00718 and 19-03-00721).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflict of interest.
Rights and permissions
About this article
Cite this article
Stolyarova, V.L., Vorozhtcov, V.A. High Temperature Study of Oxide Systems: Thermal Analysis and Knudsen Effusion Mass Spectrometry. Russ. J. Phys. Chem. 94, 2640–2647 (2020). https://doi.org/10.1134/S0036024420130257
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024420130257