Skip to main content
SpringerLink
Log in

Hybrid materials based on polymethylsilsesquioxanes containing Fe, Pt, and Fe–Pt metallic nanoparticles

  • Physical Chemistry of Nanoclusters and Nanomaterials
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

New hybrid materials based on Pt, Fe, and Pt–Fe nanoparticles stabilized in a matrix of polymethylsilsesquioxane nanogel and ultrahigh molecular weight polyethylene (UHMWPE) were prepared. Metal vapor synthesis was used to produce mono- and bimetallic nanoparticles. It was shown that organosilicon nanogel effectively stabilizes Pt nanoparticles with an average size of 0.9 nm. Using the nanogel results in the formation of superparamagnetic Fe particles 3–5 nm in size that consist of ferromagnetic Fe0 core and antiferromagnetic shells of Fe oxides. It is established that using an organosilicon matrix in the formation of Pt-Fe/UHMWPE systems helps reduce the average particle size of Fe in the material from 6.5 to 4.5 nm and narrow their particle size distribution. The composition, magnetic and electronic characteristics of the nanocomposites are studied via transmission electron microscopy, X-ray photoelectron spectroscopy, Mössbauer spectroscopy, XANES, and EXAFS.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. Jaumann, V. Rebrov, V. Kazakova, et al., Macromol. Chem. Phys. 204, 1014 (2003).

    Article  CAS  Google Scholar 

  2. X. Zhu, M. Jaumann, C. Moeller, et al., Macromolecules 39, 1701 (2006).

    Article  CAS  Google Scholar 

  3. C. Drohmann, M. Moeller, O. Gorbatsevich, et al., J. Polym. Sci., Part A: Polym. Chem. 38, 741 (2000).

    Article  CAS  Google Scholar 

  4. C. Schlenk, A. W. Kleij, H. Frey, et al., Angew. Chem., Int. Ed. Engl. 39, 3445 (2000).

    Article  CAS  Google Scholar 

  5. A. Yu. Vasil’kov, D. A. Migulin, A. V. Naumkin, et al., Mendeleev Commun. 26, 187 (2016).

    Article  Google Scholar 

  6. L. N. Nikitin, A. Yu. Vasil’kov, M. Banchero, L. Manna, A. V. Naumkin, V. L. Podshibikhin, S. S. Abramchuk, M. I. Buzin, A. A. Korlyukov, and A. R. Khokhlov, Russ. J. Phys. Chem. A 85, 1190 (2011).

    Article  CAS  Google Scholar 

  7. M. S. Rubina, A. A. Kamitov, Ya. V. Zubavichus, et al., Appl. Surf. Sci. 366, 365 (2016).

    Article  CAS  Google Scholar 

  8. M. V. Tsodikov, O. G. Ellert, S. A. Nikolaev, et al., Chem. Eng. J. 309, 628 (2017).

    Article  CAS  Google Scholar 

  9. E. E. Said-Galiev, A. Yu. Vasil’kov, A. Yu. Nikolaev, A. I. Lisitsyn, A. V. Naumkin, I. O. Volkov, S. S. Abramchuk, O. L. Lependina, A. R. Khokhlov, E. V. Shtykova, K. A. Dembo, and C. Erkey, Russ. J. Phys. Chem. A 86, 1602 (2012).

    Article  CAS  Google Scholar 

  10. A. Yu. Vasil’kov, A. V. Naumkin, I. O. Volkov, et al., Surf. Interface Anal. 42, 559 (2010).

    Article  Google Scholar 

  11. C. Evangelisti, E. Schiavi, L. A. Aronica, et al., J. Catal. 286, 224 (2012).

    Article  CAS  Google Scholar 

  12. B. L. V. Prasad, S. I. Stoeva, C. M. Sorensen, et al., J. Am. Chem. Soc. 125, 10488 (2003).

    Article  CAS  Google Scholar 

  13. G. Uccello-Barretta, F. Balzano, C. Evangelisti, et al., J. Organomet. Chem. 693, 1276 (2008).

    Article  CAS  Google Scholar 

  14. D. Migulin, E. Tatarinova, I. Meshkov, et al., J. Polym. Int, 65, 72 (2015).

    Article  Google Scholar 

  15. B. D. Karstedt, US Patent No. 3775452 (1973).

    Google Scholar 

  16. G. Vitulli, C. Evangelisti, F. Ciardelli, P. Salvadori, and F. Rocchi, EP Patent No. 1797949 A1, Bull. No. 25 (2007).

    Google Scholar 

  17. G. Uccello-Barretta, C. Evangelisti, P. Raffa, et al., J. Organomet. Chem. 694, 1813 (2009).

    Article  CAS  Google Scholar 

  18. A. Yu. Vasil’kov, B. A. Zachernyuk, Z. N. Karpikov, I.O. Volkov, Ya. V. Zubavichus, A. A. Veligzhanin, A. A. Chernyshov, M. I. Buzin, L. N. Nikitin, and V. I. Nedel’kin, Russ. J. Appl. Chem. 80, 2136 (2007).

    Article  Google Scholar 

  19. S. Laurent, D. Forge, M. Port, et al., Chem. Rev. 108, 2064 (2008).

    Article  CAS  Google Scholar 

  20. A. Yu. Vasil’kov, Yu. V. Maksimov, L. N. Nikitin, I. P. Suzdalev, A. V. Naumkin, S. S. Abramchuk, E. M. Tolstopyatov, and P. N. Grakovich, Russ. J. Phys. Chem. A 87, 985 (2013).

    Article  Google Scholar 

  21. H. Zeng, J. Li, J. P. Liu, et al., Nature 420, 395 (2002).

    Article  CAS  Google Scholar 

  22. A. A. Chernyshov, A. A. Veligzhanin, and Y. V. Zubavichus, Nucl. Instrum. Methods Phys. Res. A 603, 95 (2009).

    Article  CAS  Google Scholar 

  23. A. P. Krasnov, E. E. Said-Galiev, A. Yu. Vasil’kov, et al., RF Patent No. 2354668 (2009).

    Google Scholar 

  24. Y. X. Li and K. J. Klabunde, Hyperfine Interact. 41, 665 (1988).

    Article  CAS  Google Scholar 

  25. J. J. Schneider, N. Czap, J. Hagen, et al., Chem.-Eur. J. 6, 4305 (2000).

    Article  CAS  Google Scholar 

  26. J. Nogués, J. Sort, V. Langlais, et al., Phys. Rep. 422, 65 (2005).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 119991, Russia

    A. Yu. Vasil’kov, A. V. Naumkin, A. V. Budnikov & A. M. Muzafarov

  2. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, Moscow, 117393, Russia

    D. A. Migulin & A. M. Muzafarov

  3. National Research Center Kurchatov Institute, Moscow, 123182, Russia

    Ya. V. Zubavichus

  4. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 117901, Russia

    O. G. Ellert

  5. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 117977, Russia

    Yu. V. Maksimov

Authors
  1. A. Yu. Vasil’kov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. A. Migulin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. V. Naumkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Ya. V. Zubavichus
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. V. Budnikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. O. G. Ellert
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Yu. V. Maksimov
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. A. M. Muzafarov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. Yu. Vasil’kov.

Additional information

Original Russian Text © A.Yu. Vasil’kov, D.A. Migulin, A.V. Naumkin, Ya.V. Zubavichus, A.V. Budnikov, O.G. Ellert, Yu.V. Maksimov, A.M. Muzafarov, 2017, published in Zhurnal Fizicheskoi Khimii, 2017, Vol. 91, No. 11, pp. 1898–1905.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Vasil’kov, A.Y., Migulin, D.A., Naumkin, A.V. et al. Hybrid materials based on polymethylsilsesquioxanes containing Fe, Pt, and Fe–Pt metallic nanoparticles. Russ. J. Phys. Chem. 91, 2188–2194 (2017). https://doi.org/10.1134/S0036024417110310

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024417110310

Keywords

Search

Navigation