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Structure of the Local Environment and Hyperfine Interactions of 57Fe Probe Nuclei in AMnO3 (A = Sc, In)

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Abstract

The results of a Mössbauer study of hyperfine interactions of 57Fe probe nuclei in isostructural hexagonal manganites h-ScMnO3 and h-InMnO3 are presented. The results of measurements of the Mössbauer spectra at T > TN, as well as calculations of the parameters of the electric field gradient tensor at 57Fe nuclei, demonstrated different behavior of the probe iron ions in these isostructural systems, reflecting the difference in the processes of defect formation in their crystal lattices. On the contrary, measurements at T < TN did not reveal any differences in the local magnetic structure of 57Fe probe atoms in these oxides.

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Funding

The work was supported by the Russian Science Foundation (project no. 19-73-10034).

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Authors and Affiliations

  1. Moscow State University, 199991, Moscow, Russia

    A. V. Sobolev, S. Šandalova, I. S. Glazkova & I. A. Presniakov

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 199991, Moscow, Russia

    M. N. Smirnova

  3. Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), Namiki, 1-1, Tsukuba, 305-0044, Ibaraki, Japan

    A. A. Belik

  4. Shenzhen MSU-BIT University, 518115, Shenzhen, China

    I. A. Presniakov

Authors
  1. A. V. Sobolev
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  2. S. Šandalova
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  4. A. A. Belik
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  5. I. S. Glazkova
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Correspondence to I. S. Glazkova.

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Translated by G. Kirakosyan

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Sobolev, A.V., Šandalova, S., Smirnova, M.N. et al. Structure of the Local Environment and Hyperfine Interactions of 57Fe Probe Nuclei in AMnO3 (A = Sc, In). Russ. J. Inorg. Chem. 68, 1349–1356 (2023). https://doi.org/10.1134/S0036023623601812

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