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Synthesis and Functionalization of Unsymmetrical Terbium(III) Bis-Phthalocyaninates, Promising Components of Hybrid Magnetic Materials

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Abstract

A new unsymmetrical terbium bis-Phthalocyaninate Tb(A7B) with one terminal aliphatic OH group was obtained by template cross-condensation of diethoxyphthalonitrile (A) and phthalonitrile (B) functionalized with diethylene glycol moiety. The subsequent functionalization of the complex included the successive replacement of this OH group by the iodide and thioacetate substituents. The synthesized complexes can act as components of hybrid materials upon immobilization on surfaces of various nature.

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Funding

This study was supported by the Russian Science Foundation (grant no. 18-73-10174-P, https://rscf.ru/project/21-73-03031/).

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    A. V. Yagodin, A. G. Martynov, Yu. G. Gorbunova & A. Yu. Tsivadze

  2. Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia

    I. D. Kormshchikov

  3. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    Yu. G. Gorbunova & A. Yu. Tsivadze

Authors
  1. A. V. Yagodin
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  2. I. D. Kormshchikov
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  3. A. G. Martynov
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  4. Yu. G. Gorbunova
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  5. A. Yu. Tsivadze
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Correspondence to A. G. Martynov.

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Translated by Z. Svitanko

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Yagodin, A.V., Kormshchikov, I.D., Martynov, A.G. et al. Synthesis and Functionalization of Unsymmetrical Terbium(III) Bis-Phthalocyaninates, Promising Components of Hybrid Magnetic Materials. Russ. J. Inorg. Chem. 68, 1125–1132 (2023). https://doi.org/10.1134/S003602362360168X

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  • DOI: https://doi.org/10.1134/S003602362360168X

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