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New Coordination Compounds of Scandium Nitrate with Carbamide: Precursors for the Preparation of Nanosized Scandium Oxide

  • MODERN PROBLEMS OF COORDINATION CHEMISTRY
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Abstract

Reaction of scandium nitrate with carbamide (Ur) in aqueous solution has been studied and two previously unknown coordination compounds [Sc(H2O)(Ur)2(NO3)(μ-OH)2(NO3)(Ur)2(H2O)Sc](NO3)2 and [Sc(H2O)(Ur)4(NO3)2]NO3 have been revealed. Procedures have been developed for the synthesis of these compounds. The compounds have been studied by physicochemical methods (IR spectroscopy, X-ray powder difffraction, X-ray single-crystal diffraction, elemental analysis, thermogravimetric analysis, and differential scanning calorimetry), their composition and structure have been established. Thermolysis in wide temperature range and phase composition of thermal degradation products have been studied. It has been shown that the isolated complexes can be used for the synthesis of nanosized (20–50 nm) scandium oxide suitable as a component of modern functional materials.

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ACKNOWLEDGMENTS

Analytical studies were performed using the equipment of the Shared Facility Center, Kurchatov Institute National Research Center–IREA (supported by the Ministry of Education and Science of Russia, agreement no. 075-11-2021-070 dated August 19, 2021).

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Authors and Affiliations

  1. Institute of Fine Chemical Technology, Moscow Technological University (MIREA), 119571, Moscow, Russia

    I. A. Karavaev & E. V. Savinkina

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    M. S. Grigor’ev

  3. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    G. A. Buzanov & I. V. Kozerozhets

Authors
  1. I. A. Karavaev
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  2. E. V. Savinkina
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  3. M. S. Grigor’ev
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  4. G. A. Buzanov
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  5. I. V. Kozerozhets
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Correspondence to I. A. Karavaev.

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ADDITIONAL INFORMATION

This paper was prepared using materials of the XXVIII International Chugaev Conference on Coordination Chemistry, October 3–8, 2021, Ol’ginka, Tuapse oblast, Russia.

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Translated by I. Kudryavtsev

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Karavaev, I.A., Savinkina, E.V., Grigor’ev, M.S. et al. New Coordination Compounds of Scandium Nitrate with Carbamide: Precursors for the Preparation of Nanosized Scandium Oxide. Russ. J. Inorg. Chem. 67, 1178–1183 (2022). https://doi.org/10.1134/S0036023622080186

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