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Features of Copper(II) Oxide Synthesis in Combustion Reactions with Glycine and Citric Acid

  • SYNTHESIS AND PROPERTIES OF INORGANIC COMPOUNDS
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Abstract

Effect of citric acid (φ = 0.5–1.3) and glycine (φ = 0.5; 0.7–0.9) ratio on the rate of combustion reactions, phase composition, and particle size of CuOx powder obtained from copper nitrate solution under conditions of open and closed reactors has been considered. Modeling of combustion reactions for the synthesis of CuOx has shown that calculations of Tmax by equation derived for synthesis in combustion reactions are possible also for thermolysis or pyrolysis reactions. Formation, morphology, and dispersity of samples after completion of combustion reactions and thermal treatment at 500°C have been studied by X-ray diffraction and electron microscopy. The characteristics of combustion profiles display transition from bulk combustion mode to self-propagating high-temperature synthesis and further to thermolysis of xerogels when citric acid content increases. It has been found that retardation of redox reaction rate does not decrease CuO loss due to removal of copper within organic volatile components.

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Funding

This work was performed according to the State Assignment and Research Plans for the Institute of Solid-State Chemistry, Ural Branch, Russian Academy of Sciences, (project no. АААА-А19-119031890026-6).

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Authors and Affiliations

  1. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, 620990, Yekaterinburg, Russia

    V. D. Zhuravlev, L. V. Ermakova, Sh. M. Khaliullin, V. G. Bamburov, T. A. Patrusheva & N. M. Porotnikova

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  1. V. D. Zhuravlev
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  2. L. V. Ermakova
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  3. Sh. M. Khaliullin
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  4. V. G. Bamburov
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Correspondence to V. D. Zhuravlev.

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Translated by I. Kudryavtsev

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Zhuravlev, V.D., Ermakova, L.V., Khaliullin, S.M. et al. Features of Copper(II) Oxide Synthesis in Combustion Reactions with Glycine and Citric Acid. Russ. J. Inorg. Chem. 67, 790–798 (2022). https://doi.org/10.1134/S0036023622060250

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