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Synthesis and Study of Phases with a Hollandite-Type Structure, Crystallizing in the Systems Cs2O–M2O3(MO)–TiO2 (M = Al, Fe, Сu, Ni, Mg)

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Abstract

Ceramics based on hollandites are known to mainly produced by the conventional solid-phase method. However, the use of various sol–gel methods in some cases makes it possible to change the temperature and time its synthesis, morphological characteristics, porosity, and electrophysical properties. In this work, ceramic materials based on a number of cesium titanate hollandite phases were synthesized by combustion of citrate–nitrate mixtures. The structure of the obtained materials was studied by X-ray powder diffraction analysis and scanning electron microscopy. Investigation of the electrophysical properties showed that, in a hydrogen flow, the electrical conductivity of hollandites with aluminum and nickel increases significantly (by 2.5–3 orders of magnitude) throughout the studied temperature range. Thus, ceramics based on these hollandites can be considered promising for creating hydrogen sensors and fuel cells.

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Funding

This work was performed under a State Assignment for the Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, St. Petersburg, Russia (subject no. 0081-2022-0008).

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Authors and Affiliations

  1. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia

    O. Yu. Sinel’shchikova, N. V. Besprozvannykh, D. A. Rogova, S. K. Kuchaeva & O. L. Galankina

  2. Institute of Precambrian Geology and Geochronology, Russian Academy of Sciences, 199034, St. Petersburg, Russia

    O. L. Galankina

Authors
  1. O. Yu. Sinel’shchikova
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  2. N. V. Besprozvannykh
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Correspondence to O. Yu. Sinel’shchikova.

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Translated by V. Glyanchenko

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Sinel’shchikova, O.Y., Besprozvannykh, N.V., Rogova, D.A. et al. Synthesis and Study of Phases with a Hollandite-Type Structure, Crystallizing in the Systems Cs2O–M2O3(MO)–TiO2 (M = Al, Fe, Сu, Ni, Mg). Russ. J. Inorg. Chem. 67, 963–969 (2022). https://doi.org/10.1134/S0036023622060213

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