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Modification of HfB2–30% SiC UHTC with Graphene (1 vol %) and Its Influence on the Behavior in a Supersonic Air Jet

  • INORGANIC MATERIALS AND NANOMATERIALS
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Abstract

Oxidation under exposure to a supersonic dissociated air jet (with heat fluxes in the range 363–779 W/cm2, total exposure time: 2000 s) was studied for HfB2–30 vol % SiC ultra-high-temperature ceramics (UHTC) doped with a lowered amount (1 vol %) of reduced graphene oxide (GO). Doping the ceramics with a relatively low amount of reduced GO (1 vol %) did not prevent a dramatic increase in the average surface temperature to 2300–2400°С. However, the existence time of surface temperatures below 1800–1850°С increased considerably, probably due to an increase in the thermal conductivity of the ceramics. The ablation rate of the material was determined as 6.5 × 10–4 g/(cm2 min), which is intermediate between the respective values for HfB2–SiC ceramics and the ceramics doped by 2 vol % graphene. The microstructure features and elemental composition of the oxidized surface and chips of the material were studied. The structure and thickness of the oxidized near-surface region were determined.

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ACKNOWLEDGMENTS

The study of the evolution of the microstructure and phase composition of the samples as a result of oxidation was carried out using the equipment of the Center for Shared Use of Physical Methods for Researching Substances and Materials of the Kurnakov Institute RAS, which was supported by the Ministry of Science and Higher Education of the Russian Federation as part of the State Assignment of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences.

Funding

The studies of the thermochemical behavior of graphene-doped samples was supported by the Russian Foundation for Basic Research (project No. 20-01-00056). The experiment on a VGU-4 MW plasma torch was in part supported by the Government assignment to the Ishlinskii Institute of Problems of Mechanics (project No. AAAA-A20–120011690135-5: modification of measurement systems).

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    E. P. Simonenko, N. P. Simonenko, I. A. Nagornov, V. G. Sevastyanov & N. T. Kuznetsov

  2. Ishlinskii Institute of Problems of Mechanics, Russian Academy of Sciences, 119526, Moscow, Russia

    A. F. Kolesnikov & A. V. Chaplygin

  3. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, 119334, Moscow, Russia

    A. S. Lysenkov

  4. Mendeleev Russian University of Chemical Technology, 125047, Moscow, Russia

    I. A. Nagornov

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  1. E. P. Simonenko
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Simonenko, E.P., Simonenko, N.P., Kolesnikov, A.F. et al. Modification of HfB2–30% SiC UHTC with Graphene (1 vol %) and Its Influence on the Behavior in a Supersonic Air Jet. Russ. J. Inorg. Chem. 66, 1405–1415 (2021). https://doi.org/10.1134/S003602362109014X

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