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Study of lithium complexes with benzo-15-crown-5 ether by X-ray diffraction and IR spectroscopy

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Abstract

The complex formation of lithium with benzo-15-crown-5 (B15C5) was investigated. The complexes LiB15C5H2OX, where X = Cl− (1), I− (2), (3), (5), and LiBF4B15C5 (4) were synthesized and studied by IR spectroscopy. Complexes 1–4 were examined by X-ray diffraction. According to IR spectroscopy data, the crown ether conformation changes upon dissolution. The interaction of the extracted complex with the solvent was identified.

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References

  1. M. Tanigawa, S. Nishiyama, S. Tsuruya, and M. Masai, Chem. Eng. J. 39, 157 (1988). doi 10.1016/0300-9467(88)80023-6

    Article  CAS  Google Scholar 

  2. S. V. Demin, V. I. Zhilov, A. Yu. Tsivadze, Russ. J. Inorg. Chem. 60, 633 (2015). doi 10.1134/S0036023615050046

    Article  CAS  Google Scholar 

  3. S. V. Demin, V. I. Zhilov, A. Yu. Tsivadze, Russ. J. Inorg. Chem. 61, 119 (2016). doi 10.1134/S0036023616010071

    Article  CAS  Google Scholar 

  4. SMART and SADABS Software Reference Manuals, Bruker AXS, Inc., Madison, Wisconsin, USA, 1998.

  5. SAINT, version 6.02A, Bruker AXS, Inc., Madison, Wisconsin, USA, 2001.

  6. SHELXTL-Plus, version 5.10, Bruker AXS, Inc., Madison, Wisconsin, USA, 1997.

  7. O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, et al., J. Appl. Crystallogr. 42, 339 (2009). doi 10.1107/ S0021889808042726

    Article  CAS  Google Scholar 

  8. A. Nurtaeva and E. M. Holt, Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 55, 1453 (1999). doi 10.1107/ S0108270199007040

    Article  Google Scholar 

  9. X. Yang, C. B. Knobler, Zh. Zheng, and M. F. Hawthorne, J. Am. Chem. Soc. 116, 7142 (1994). doi 10.1021/ja00095a018

    Article  CAS  Google Scholar 

  10. M.-L. Lehaire, R. Scopelliti, and K. Severin, Inorg. Chem. 41, 5466 (2002). doi 10.1021/ic025749k

    Article  CAS  Google Scholar 

  11. Y. G. Andreev, V. Seneviratne, M. Khan, et al., Chem. Mater. 17 (4), 767 (2005). doi 10.1021/cm048310u

    Article  CAS  Google Scholar 

  12. M.-L. Lehaire, R. Scopelliti, H. Piotrowski, and K. Severin, Angew. Chem., Int. Ed. Engl. 41 (8), 1419 (2002). doi 10.1002/1521-3773(20020415)41:8〈1419::AIDANIE1419〉 3.0.CO;2-L

    Article  CAS  Google Scholar 

  13. J. A. Cissell, T. P. Vaid, and G. P. A. Yap, Org. Lett. 8 (14), 2401 (2006). doi 10.1021/ol060772l

    Article  CAS  Google Scholar 

  14. A. Ramirez, E. Lobkovsky, and D. B. Collum, J. Am. Chem. Soc. 125, 15376 (2003). doi 10.1021/ja030322d

    Article  CAS  Google Scholar 

  15. A. Yu. Tsivadze, A. A. Varnek, and V. E. Khutorskii, Metal Coordination Compounds with Crown Ligands (Nauka, Moscow, 1991) [in Russian].

    Google Scholar 

  16. V. A. Trofimov, I. K. Kireeva, N. B. Generalova, and A. Yu. Tsivadze, Koord. Khim. 16, 1458 (1990).

    CAS  Google Scholar 

  17. I. K. Kireeva, N. B. Generalova, V. A. Trofimov, and A. Yu. Tsivadze, Zh. Neorg. Khim. 36, 1464 (1991).

    CAS  Google Scholar 

  18. N. A. Shokurova, L. I. Demina, V. I. Zhilov, et al., Russ. J. Inorg. Chem, 61, 787 (2016). doi 10.1134/S0036023616060176

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, 119071, Russia

    L. I. Demina, S. V. Demin, N. A. Shokurova, V. I. Zhilov & A. Yu. Tsivadze

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    L. I. Demina, L. G. Kuz’mina, S. V. Demin, V. I. Zhilov & A. Yu. Tsivadze

Authors
  1. L. I. Demina
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  2. L. G. Kuz’mina
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  3. S. V. Demin
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  4. N. A. Shokurova
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  5. V. I. Zhilov
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  6. A. Yu. Tsivadze
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Corresponding author

Correspondence to V. I. Zhilov.

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Original Russian Text © L.I. Demina, L.G. Kuz’mina, S.V. Demin, N.A. Shokurova, V.I. Zhilov, A.Yu. Tsivadze, 2017, published in Zhurnal Neorganicheskoi Khimii, 2017, Vol. 62, No. 11, pp. 1535–1543.

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Demina, L.I., Kuz’mina, L.G., Demin, S.V. et al. Study of lithium complexes with benzo-15-crown-5 ether by X-ray diffraction and IR spectroscopy. Russ. J. Inorg. Chem. 62, 1536–1543 (2017). https://doi.org/10.1134/S0036023617110031

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  • DOI: https://doi.org/10.1134/S0036023617110031

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