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Synergistic Effect for a Mixture of 3-Butyl-5-Amino-6-Methyluracil and Butylated Hydroxytoluene during Inhibited Styrene Autoxidation

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Abstract

The antioxidant effect of a mixture of 3-butyl-5-amino-6-methyluracil and butylated hydroxytoluene (BHT) was studied in a model system of initiated radical chain oxidation of styrene in chlorobenzene at 310 K. The maximum synergistic effect was observed at a ratio of ~0.75 between uracil derivative and BHT concentrations. The mechanism of synergistic action was discussed.

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ACKNOWLEDGMENTS

This work was performed with the use of the equipment of the Chemistry Center for Collective Use at the Ufa Institute of Chemistry, Russian Academy of Sciences.

Funding

This work was carried out within the framework of a state contract “Oxidation Processes with the Participation of Reactive Oxygen Species” no. AAAA-A20-120012090025-2.

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Authors and Affiliations

  1. Ufa Institute of Chemistry, Russian Academy of Sciences, 450054, Ufa, Bashkortostan, Russia

    A. V. Antipin, S. A. Grabovskii, Yu. S. Grabovskaya & N. N. Kabal’nova

Authors
  1. A. V. Antipin
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  2. S. A. Grabovskii
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  3. Yu. S. Grabovskaya
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  4. N. N. Kabal’nova
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Corresponding author

Correspondence to A. V. Antipin.

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The authors have no conflicts of interest.

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Translated by V. Makhlyarchuk

Abbreviations: AIBN, 2,2'-azobisisobutyronitrile; BHT, butylated hydroxytoluene; St, styrene; α‑TP, α-tocopherol.

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Antipin, A.V., Grabovskii, S.A., Grabovskaya, Y.S. et al. Synergistic Effect for a Mixture of 3-Butyl-5-Amino-6-Methyluracil and Butylated Hydroxytoluene during Inhibited Styrene Autoxidation. Kinet Catal 61, 369–373 (2020). https://doi.org/10.1134/S0023158420030027

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  • DOI: https://doi.org/10.1134/S0023158420030027

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