Abstract
New phenolate and azide bridged tetranuclear zinc(II) complex [Zn4Br2L2(μ1,1-N3)2] (1) and new mononuclear copper(II) complex [CuL] (2), where L is the dianionic form of N,N′-bis(5-methylsalicylidene)-1,3-propanediamine (H2L), are synthesized and characterized. The complexes are characterized by elemental analyses, IR, UV-Vis spectra, molar conductivity, and single crystal X-ray diffraction. X-ray analysis indicates that the Zn atoms in complex 1 are in tetrahedral and square pyramidal coordinations, and the Cu atom in complex 2 is in a tetrahedral distorted square planar coordination. In the crystal structures of the complexes, molecules are stacked through π⋯π interactions. The complexes are assayed for antibacterial activities against three gram-positive bacterial strains (E. cloacae, E. cloacae, and St. faecalis) and three gram-negative bacterial strains (St. faecalis, P. aeruginosa, and E. cloacae) by the MTT method.
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This project was supported by the Henan Province Universities and Colleges Funded Scheme (21A530010).
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Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 7, pp. 1208-1215.https://doi.org/10.26902/JSC_id76142
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Qian, H.Y. SYNTHESIS, X-RAY CRYSTAL STRUCTURES, AND ANTIBACTERIAL ACTIVITY OF ZINC(II) AND COPPER(II) COMPLEXES DERIVED FROM N,N′-BIS(5-METHYLSALICYLIDENE)-1,3-PROPANEDIAMINE. J Struct Chem 62, 1131–1138 (2021). https://doi.org/10.1134/S0022476621070180
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DOI: https://doi.org/10.1134/S0022476621070180