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Hydrothermal synthesis of a nano-rod mercury(ii) metal-ligand coordination compound

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Abstract

A novel nano-rod mercury(II) coordination compound [Hg (BINH)I2] (1), (BINH is the abbreviation of benzylideneisonicotinohydrazide) is synthesized by a hydrothermal method that produces the coordination compound at a nanosize level. The new nanostructure is characterized by scanning electron microscopy, powder X-ray diffraction, elemental analysis, and IR spectroscopy. Compound 1 was structurally characterized by single crystal X-ray diffraction and the single-crystal structure of this complex shows that each mercury(II) center is four-coordinated with two N-donor atoms from tow BINH ligands and tow iodo anions. Self-assembly of this complexes is pereformed by CH⋯I and π-π stacking interactions. The supramolecular features in these complexes are controlled by weak directional intermolecular interactions.

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Authors and Affiliations

  1. School of Mechanical Engineering, WCU Nano Research Center, Yeungnam University, Gyongsan, South Korea

    Y. Hanifehpour & Sang Woo Joo

  2. Research Laboratory of Advanced Water and Wastewater Treatment Processes, Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran

    A. Khataee

  3. Center for Research Facilities, Yeungnam University, Gyongsan, South Korea

    Bong-Ki Min

Authors
  1. Y. Hanifehpour
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  2. A. Khataee
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  3. Sang Woo Joo
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  4. Bong-Ki Min
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Corresponding author

Correspondence to Y. Hanifehpour.

Additional information

Original Russian Text © 2014 Y. Hanifehpour, A. Khataee, Sang Woo Joo, Bong-Ki Min.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 55, No. 3, pp. 597–602, May–June, 2014.

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Hanifehpour, Y., Khataee, A., Joo, S.W. et al. Hydrothermal synthesis of a nano-rod mercury(ii) metal-ligand coordination compound. J Struct Chem 55, 570–575 (2014). https://doi.org/10.1134/S0022476614030275

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  • DOI: https://doi.org/10.1134/S0022476614030275

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