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Modeling Iron Pentacarbonyl Vaporization Accompanied by Vapor Condensation on a Flowing Down Liquid Film

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Inorganic Materials Aims and scope

Abstract

Using iron pentacarbonyl distillation as an example, we analyze the vaporization process in a closed vaporization–condensation system where vapor condenses on a flowing down liquid film. We jointly analyze the mechanisms behind vaporization, vapor transport, condensation, and flowing of the condensate on the inner surface of a vertical tube. We calculate the thickness of the flowing down liquid film, determine the vaporization coefficient for a closed system using experimentally determined temperature dependences of the vaporization rate and saturated vapor pressure, and present the vaporization rate as a function of the vaporization and condensation temperatures, the radius and height of the condensation tube, and the vaporization area of the still residue.

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Authors and Affiliations

  1. Devyatykh Institute of Chemistry of High-Purity Substances, Russian Academy of Sciences, ul. Tropinina 49, Nizhny Novgorod, 603950, Russia

    V. A. Shaposhnikov, Yu. S. Belozerov, Yu. P. Kirillov, A. D. Bulanov & M. F. Churbanov

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  1. V. A. Shaposhnikov
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  2. Yu. S. Belozerov
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  3. Yu. P. Kirillov
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  4. A. D. Bulanov
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  5. M. F. Churbanov
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Corresponding author

Correspondence to Yu. P. Kirillov.

Additional information

Original Russian Text © V.A. Shaposhnikov, Yu.S. Belozerov, Yu.P. Kirillov, A.D. Bulanov, M.F. Churbanov, 2018, published in Neorganicheskie Materialy, 2018, Vol. 54, No. 9, pp. 929–935.

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Shaposhnikov, V.A., Belozerov, Y.S., Kirillov, Y.P. et al. Modeling Iron Pentacarbonyl Vaporization Accompanied by Vapor Condensation on a Flowing Down Liquid Film. Inorg Mater 54, 878–884 (2018). https://doi.org/10.1134/S0020168518090157

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  • DOI: https://doi.org/10.1134/S0020168518090157

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