Abstract
Based on the experimental data obtained by the authors in a number of previous studies, the limits of applicability of positron annihilation lifetime spectroscopy (PALS) and low-temperature gas sorption (LTGS) to determination of nanoporosity (size distribution of nanopores in the range from a few fractions of a nanometer to 50 nm) in polymeric membrane materials and sorbents are discussed. It turns out that none of these methods is universal. The possibility of using each of them is determined by different factors, with the cases considered being finely divided polymer materials and the membranes per se cast from powders. It has been shown that the particle size factor is important for the applicability of LTGS. The possibility of using PALS depends on the concentration of nanopores of a given size.
Similar content being viewed by others
References
Weber M.H. and Lynn, K.G., Principles and Applications of Positron and Positronium Chemistry, Jean, Y.C., Mallon, P.E., and Schrader, D.M., Eds., River Edge, NJ: World Scientific, 2003, p. 167.
Shantarovich, V.P., J. Polym. Sci., Part B: Polym. Phys., 2008, vol. 45, p. 2485.
Yampolskii, Yu.P., Usp. Khim., 2007, vol. 76, no. 1, p. 66.
Eldrup, M., Lightbody, D., and Sherwood, J.N., Chem. Phys., 1981, vol. 63, p. 51.
Burganos, V.N., Comprehensive Membrane Science and Engineering, Drioli, E. and Giorno, L., Eds., Amsterdam: Elsevier, 2010, vol. 1, p. 29.
Jasinska, B., Koziol, A., and Goworek, T., J. Radoanal. Nucl. Chem., 1996, vol. 210, p. 617.
Mogensen, O.E., Positron Annihilation in Chemistry, Goldanskii, V.I. and Schaffer, F.P., Eds., Berlin: Springer, 1995, p. 66.
Stepanov, S.V. and Byakov, Principles and Applications of Positron and Positronium Chemistry, Jean, Y.C., Mallon, P.E., and Schrader, D.M., Eds., River Edge, NJ: World Scientific, 2003, p. 117.
Shantarovich, V.P., Gustov, V.W., Belousova, E.V., Polyakova, A.V., Bekeshev, V.G., Kevdina, I.B., Yam-polskii, Yu.P., and Pastukhov, A.V., Acta Phys. Pol., A, 2014, vol. 125, p. 806.
Shantarovich, V.P., Bekeshev, V.G., Belov, N.A., Nikolaev, A.Yu., Gustov, V.W., Kevdina, I.B., and Filimonov, M.K., High Energy Chem., 2016, vol. 50, no. 4, p. 287.
Shantarovich, V.P., Bekeshev, V.G., Belov, N.A., Kevdina, I.B., Filimonov, M.K., Ronova, I.A., and Nikolaev, A.Yu., Defect Diffus. Forum, 2016, vol. 373, p. 261.
Shantarovich, V.P., Bekeshev, V.G., Pastukhov, A.V., Davankov, V.A., Krasil’nikova, O.K., Belousova, E.V., Kevdina, I.B., Filimonov, M.K., and Gustov, V.W., J. Phys.: Conf. Ser., 2015, vol. 618, p. 012021.
Belousova, E.V., Bekeshev, V.G., Gustov, V.V., Davankov, V.A., Krasil’nikova, O.K., Kevdina, I.B., Pastukhov, A.V., Filimonov, M.K., and Shantarovich, V.P., High Energy Chem., 2015, vol. 49, no. 3, p. 199.
Shantarovich, V.P., Bekeshev, V.G., Kevdina, I.B., Yampolskii, Yu.P., Bermeshev, M.V., and Belov, N.A., Acta Phys. Pol., A, 2017, vol. 132, no. 5, p. 1518.
Kirkegaard, P., Pedersen, N.J., and Eldrup, M.M., PATFIT-88: A Data-Processing System for Positron Annihilation Spectra on Mainframe and Personal Computers (Risø-M; No. 2740), Kongens Lyngby: Technical University of Denmark, 1989.
Duda, J.L. and Zielinski, J.M., Diffusion in Polymers, P. Neogi, Ed., New York: Marcel Dekker, 1996, p. 143.
Sing, K.S.W., Surface Area Determination, Everett, D.H. and Ottervill, R.H., Eds., London: Butterworth, 1970, p. 25.
Barrett, E.P., Joyner, L.G., and Halenda, P.P., J. Am. Chem. Soc., 1951, vol. 73, p. 373.
Horwath, G. and Kawazoe, K., J. Chem. Eng. Jpn., 1983, vol. 16, no. 6, p. 470.
Ronova, I.A., Nikitin, L.N., Sokolova, E.A., Bacosca, I., Sava, I., and Bruma, M., J. Macromol. Sci., 2009, vol. 46, p. 929.
Vyacheslavov, A.S. and Efremov, M., Metodicheskaya razrabotka MGU im. Lomonosova: Opredelenie ploshchadi poverkhnosti i poristosti materialov metodom sorbtsii gazov (Guidelines for Determining Surface Area and Porosity of Materials by the Gas Sorption Method), Moscow, MGU im. Lomonosova, 2011.
NOVA Operating Manual, Boynton Beach, FL: Quantachrome Instruments, 2005.
NOVAWIN2 V.2.1.: Operating Manual, Boynton Beach, FL: Quantachrome Instruments, 2004.
Saito, A. and Foley, H.C., AIChE J., 1991, vol. 37, no. 3, p. 429.
Gregg, S.J. and Sing, K.S.W., Adsorption, Surface Area and Porosity, London: Academic, 1982, 2nd ed.
Gun’ko, V.M., Leboda, R., Skubishevska-Zieba, J., Gawdzik, B., and Charmas, B., Appl. Surf. Sci., 2005, vol. 252, p. 612.
Heuchel, M., Fritsch, D., Budd, P.M., and McKeown, D., Hofmann, J. Membr. Sci., 2008, vol. 318, p. 84.
McKeown, N.B., Budd, P.M., Msayib, K.J., Ghanem, B.S., Kingston, H.J., Tattershall, C.E., Makhseed, S., Reynolds, K.J., and Fritsch, D., Chem.-Eur., 2005, vol. 11, p. 2610.
Budd, P.M, McKeown, N.B., Fritsch D., Yampolskii Yu., and Shantarovich, V., Membrane Gas Separation, Yampolskii, Yu. and Freeman, B., Singapore: Wiley, 2010, p. 30.
Gidley, D.W., Peng, H.G., and Vallery, R.S., Annu. Rev. Mater. Res., 2006, vol. 36, p. 49.
Shantarovich, V.P., Novikov, Yu.A., Suptel, Z.K., Kevdina, I.B., Khotimskii, V.S., and Yampolskii, Yu.P., Radiat. Phys. Chem., 2000, vol. 58, p. 513.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © V.P. Shantarovich, V.G. Bekeshev, I.B. Kevdina, Yu.P. Yampolskii, M.V. Bermeshev, N.A. Belov, 2018, published in Khimiya Vysokikh Energii, 2018, Vol. 52, No. 4.
Rights and permissions
About this article
Cite this article
Shantarovich, V.P., Bekeshev, V.G., Kevdina, I.B. et al. Nanoporosity of Polymer Membrane Materials and Sorbents According to Positron Annihilation and Low-Temperature Gas Sorption Data. High Energy Chem 52, 275–282 (2018). https://doi.org/10.1134/S0018143918040148
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0018143918040148