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Oxidative conversion of cyclohexane in discharge plasma maintained with different high-voltage power sources

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Abstract

The influence of the pulse parameters of supply voltage in a barrier discharge reactor on the yield of incomplete oxidation of cyclohexane was studied. It was shown that the voltage pulse parameters have an insignificant effect on both the product composition of cyclohexane oxidation and on selectivity for the products cyclohexanone (40.8%), cyclohexanol (49.5%), and water (9.7%). The lowest power consumption for the conversion of cyclohexane was achieved with the use of a sine wave generator operating at a frequency of 50 Hz (3.0 kWh kg−1) and a harmonic generator with a pulse duration of 15.3 μs and a pulse repetition frequency of 980 Hz (3.5 kWh kg−1). The space mode of barrier discharge was realized with the use of a generator of microsecond (53 μs) alternating voltage pulses.

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References

  1. Kudryashov, S.V., Shchegoleva, G.S., Sirotkina, E.E., and Ryabov, A.Yu., Khim. Vys. Energ., 2000, vol. 34, no. 2, p. 145 [High Energy Chem., 2000, vol. 34, no. 2, p. 112].

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  2. Samoilovich, V.G., Gibalov, V.I., and Kozlov, K.V., Fizicheskaya khimiya bar’ernogo razryada (Physical Chemistry of a Barrier Discharge), Moscow: Mosk. Gos. Univ., 1989.

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Authors and Affiliations

  1. Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences, Akademicheskii pr. 3, Tomsk, 634055, Russia

    S. V. Kudryashov, A. Yu. Ryabov, G. S. Shchegoleva & V. Yu. Savinykh

  2. High Current Electronics Institute, Siberian Branch, Russian Academy of Sciences, Akademicheskii pr. 2/3, Tomsk, 634055, Russia

    A. I. Suslov

Authors
  1. S. V. Kudryashov
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  2. A. Yu. Ryabov
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  3. G. S. Shchegoleva
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  4. V. Yu. Savinykh
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  5. A. I. Suslov
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Correspondence to S. V. Kudryashov.

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Original Russian Text © S.V. Kudryashov, A.Yu. Ryabov, G.S. Shchegoleva, V.Yu. Savinykh, A.I. Suslov, 2008, published in Khimiya Vysokikh Energii, 2008, Vol. 42, No. 1, pp. 56–60.

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Kudryashov, S.V., Ryabov, A.Y., Shchegoleva, G.S. et al. Oxidative conversion of cyclohexane in discharge plasma maintained with different high-voltage power sources. High Energy Chem 42, 51–55 (2008). https://doi.org/10.1134/S0018143908010104

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  • DOI: https://doi.org/10.1134/S0018143908010104

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