Abstract
A study of the influence of a small impurity of cobalt oxide CoO on the magnetic properties of graphite nanopowder is presented in this article. It is shown that such an impurity is responsible for the weak ferromagnetism of a sample freshly prepared and annealed at 670 K in air, which substantially increases after vacuum annealing. The effect of an exchange bias caused by the partial reduction of antiferromagnetic CoO particles to metallic cobalt, which is a ferromagnet, is discovered.
REFERENCES
Kopelevich, Y., Esquinazi, P., Torres, J.H.S., and Moehlecke, S., Ferromagnetic- and superconducting-like behavior of graphite, J. Low Temp. Phys., 2000, vol. 5, no. 119, pp. 691–702.
Esquinazi, P., Setzer, A., Höhne, R., Semmelhack, C., Kopelevich, Y., Spemann, D., Butz, T., Kohlst-runk, B., and Lösche, M., Ferromagnetism in oriented graphite samples, Phys. Rev. B, 2002, vol. 66, no. 2, p. 024429.
Wang, Y., Huang, Y., Song, Y., Zhang, X., Ma, Y., Liang, J., and Chen, Y., Room-temperature ferromagnetism of graphene, Nano Lett., 2009, vol. 9, no. 1, pp. 220–224.
Fayazi, M., Liu, B., Lei, L., Shuai, G., Odunm-baku, O., Wang, S., He, Y., and Boi, F.S., Ferromagnetic hysteresis and structural recrystallization in turbostratic graphite, Mater. Res. Express, 2019, vol. 6, no. 10, p. 105612.
Miao, X., Tongay, S., and Hebard, A.F., Extinction of ferromagnetism in highly ordered pyrolytic graphite by annealing, Carbon, 2012, vol. 50, no. 4, pp. 1614–1618.
Haruyama, J., Graphene and graphene nanomesh spintronics, Electronics, 2013, vol. 2, no. 4, pp. 368–386.
Saad, M., Gilmutdinov, I.F., Rogov, A.M., Nikitin, S.I., Tayurskii, D.A., and Yusupov, R.V., Ferromagnetism and persistent currents in finely dispersed highly oriented pyrolytic graphite samples, Russ. Phys. J., 2018, vol. 61, no. 7, pp. 1247–1251.
Wang, C. and Diao, D., Magnetic behavior of graphene sheets embedded carbon film originated from graphene nanocrystallite, Appl. Phys. Lett., 2013, vol. 102, no. 5, p. 052402.
Saad, M., Gilmutdinov, I.F., Kiiamov, A.G., Tayurskii, D.A., Nikitin, S.I., and Yusupov, R.V., Observation of persistent currents in finely dispersed pyrolytic graphite, JETP Lett., 2018, vol. 107, no. 1, pp. 42–46.
Wood, R.A., Lewis, M.H., Lees, M.R., Benning-ton, S.M., Cain, M.G., and Kitamura, N., Ferromagnetic fullerene, J. Phys.: Condens. Matter, 2002, vol. 14, no. 22, p. L385.
Ma, Y.W., Lu, Y.H., Yi, J.B., Feng, Y.P., Herng, T.S., Liu, X., Gao, D.Q., Xue, D.S., Xue, J.M., Ouy-ang, J.Y., and Ding, J., Room temperature ferromagnetism in Teflon due to carbon dangling bonds, Nat. Commun., 2012, vol. 3, no. 1, pp. 1–8.
Milev, A., Dissanayake, D.M.A.S., Kannangara, G.S.K., and Kumarasinghe, A.R., Defect induced electronic states and magnetism in ball-milled graphite, Phys. Chem. Chem. Phys., 2013, vol. 15, no. 38, pp. 16294–16302.
Ma, S., Xia, J.H., Srikanth, V.V., Sun, X., Staedler, T., Jiang, X., Yang, F., and Zhang, Z.D., Magnetism of amorphous carbon nanofibers, Appl. Phys. Lett., 2009, vol. 95, no. 26, p. 263105.
Sharpe, A.L., Fox, E.J., Barnard, A.W., Finney, J., Watanabe, K., Taniguchi, T., Kastner, M.A., and Goldhaber-Gordon, D., Emergent ferromagnetism near three-quarters filling in twisted bilayer graphene, Science, 2019, vol. 365, no. 6453, pp. 605–608.
Yazyev, O.V., Emergence of magnetism in graphene materials and nanostructures, Rep. Prog. Phys., 2010, vol. 73, no. 5, p. 056501.
Magda, G.Z., Jin, X., Hagymási, I., Vancsó, P., Osváth, Z., Nemes-Incze, P., Hwang, C., Biro, L.P., and Tapaszto, L., Room-temperature magnetic order on zigzag edges of narrow graphene nanoribbons, Nature, 2014, vol. 514, no. 7524, pp. 608–611.
Sepioni, M., Nair, R.R., Tsai, I.L., Geim, A.K., and Grigorieva, I.V., Revealing common artifacts due to ferromagnetic inclusions in highly oriented pyrolytic graphite, Europhys. Lett., 2012, vol. 97, no. 4, p. 47001.
Morales, C., Díaz-Fernández, D., Prieto, P., Lu, Y.H., Kersell, H., del Campo, A., Escudero, C., Pérez-Dieste, V., Ashby, P., Méndez, J., and Soriano, L., In-situ study of the carbon gasification reaction of highly oriented pyrolytic graphite promoted by cobalt oxides and the novel nanostructures appeared after reaction, Carbon, 2020, vol. 158, pp. 588–597.
Meiklejohn, W.H. and Bean, C.P., New magnetic anisotropy, Phys. Rev., 1956, vol. 102, no. 5, p. 1413.
ACKNOWLEDGMENTS
The authors are grateful to A.M. Rogov and V.G. Evtyugin for the characterization of the samples using electron microscopy.
Funding
The study was carried out at the expense of a subsidy allocated to Kazan Federal University for the fulfillment of the state task in the field of scientific activity no. FZSM-2020-0050.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by S. Rostovtseva
Rights and permissions
About this article
Cite this article
Saad, M., Kiiamov, A.G., Nikitin, S.I. et al. Ferromagnetism of Graphite Nanopowders with Cobalt Oxide Impurity and Its Evolution at Moderate Annealing. Inorg. Mater. Appl. Res. 14, 118–122 (2023). https://doi.org/10.1134/S207511332301032X
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S207511332301032X