Abstract
The fractal characteristics of individual macromolecular tangles of block and random copolymers are investigated. It was found that the dependence of the mass of macromolecules on the radius of inertia of a statistically significant sample is well described by the de Gennes equation with a fractal dimension of 5/3. It was established that the fine structure of the polymer coil also has a fractal nature. The fractal dimension inside the macromolecular coil changes significantly with distance from the center of mass.
Similar content being viewed by others
REFERENCES
Mandelbrot, B.B., Les Objects Fractals: Forme, Hasard et Dimension, Paris: Flammarion, 1975.
Feder, E., Fractals, New York: Plenum Press, 1988.
Fractals in Physics, Tosatti, E. and Pietronero, L., Eds., Amsterdam: North-Holland, 1986.
Roldugin, V.I., Usp. Khim., 2003, vol. 72, no. 10, p. 931.
Roldugin, V.I., Usp. Khim., 2003, vol. 72, no. 11, p. 1027.
Mandelbrot, B.B., The Fractal Geometry of Nature, San-Francisco, CA: W.H. Freeman and Co., 1982.
Balankin, A.S., Sinergetika deformiruemogo tela (Synergetics of Deforming Body), Moscow: Ministry of Defense of the USSR, 1991.
Kozlov, G.V. and Novikov, V.U., Sinergetika i fraktal’nyi analiz setchatykh polimerov (Synergetics and Fractal Analysis of Network Polymers), Moscow: Klassika, 1998.
Shogenov, V.N. and Kozlov, G.V., Fraktal’nye klastery v fiziko-khimii polimerov (Fractal Clusters for Physical Chemistry of Polymers), Nalchik: Poligrafservis i T., 2002.
Ivanova, V.S., Kuzeev, I.R., and Zakirnichnaya, M.M., Sinergetika i fraktaly. Universal’nost’ mekhanicheskogo povedeniya materialov (Synergetics and Fractals. Universality of Mechanical Behavior for Materials), Ufa: Ufa State Petroleum Technical Univ., 1988.
Zemlyanov, M.G., Malinovskii, V.K., Novikov, V.N., Parshin, P.P., and Sokolov, A.P., Zh. Eksp. Teor. Fiz., 1992, vol. 101, no. 1, p. 284.
Gorshkova, O.V., Cand. Sci. (Chem.) Dissertation, Moscow: A.N. Frumkin Institute of Physical Chemistry and Electrochemistry Russ. Acad. Sci., 2010.
Gorshkova, O.V., Chalykh, A.E., Gerasimov, V.K., et al., Nelineinyi Mir, 2009, vol. 7, no. 10, p. 772.
Chalykh, A.E., Gerasimov, V.K., Gorshkova, O.V., et al., Kauch. Rezina, 2017, vol. 76, no. 3, p. 138.
Chalykh, A.E., Gerasimov, V.K., Gorshkova, O.V., et al., Kauch. Rezina, 2017, vol. 76, no. 3, p. 144.
de Gennes, P.-G., Scaling Concepts in Polymer Physics, Ithaca, NY, London: Cornell Univ. Press, 1980.
Dashevskii, V.G., Konformatsionnyi analiz makromolekul (Conformational Analysis for Macromolecules), Moscow: Nauka, 1987.
Busygin, V.B., Cand. Sci. (Chem.) Dissertation, Moscow: Institute of Physical Chemistry USSR Acad. Sci., 1989.
Alekseenko, T.V., Cand. Sci. (Chem.) Dissertation, Moscow: Institute of Physical Chemistry Russ. Acad. Sci., 1995.
Vishnevskii, A.S., Chalykh, A.E., Gerasimov, V.K., et al., Vestn. Kazan.Tekhnol. Univ., 2017, vol. 20, no. 6, p. 15.
Vishnevskii, A.S., Chalykh, A.E., Pisarev, S.A., et al., Prot. Met. Phys. Chem. Surf., 2017, vol. 53, no. 2, p. 241.
Gerasimov, V.K. and Chalykh, A.E., Polym. Sci., Ser. B, 2001, vol. 43, nos. 11–12, p. 307.
Grosberg, A.Yu. and Khokhlov, A.R., Statisticheskaya fizika makromolekul (Statistical Physics for Macromolecules), Moscow: Nauka, 1989.
Semchikov, Yu.L., Vysokomolekulyarnye soedineniya (High-Molecular Compounds), Nizhny Novgorod: Lobachevsky State University of Nizhny Novgorod, 1993.
Nesterov, A.E. and Lipatov, Yu.S., Termodinamika rastvorov i smesei polimerov (Thermodynamics of Solutions and Polymer Blends), Kiev: Naukova Dumka, 1984.
Klenin, V.I., Termodinamika sistem s gibkotsepnymi polimerami (Thermodynamics of Systems with Flexible Polymers), Saratov: Saratov State Univ., 1995.
Kuleznev, V.N., Smesi polimerov (Polymer Blends), Moscow: Khimiya, 1980.
Gerasimov, V.K., Doctoral Sci. (Chem.) Dissertation, Moscow: A.N. Frumkin Institute of Physical Chemistry and Electrochemistry Russ. Acad. Sci., 2012.
ACKNOWLEDGMENTS
The studies were performed using the equipment of Shared Use Center at the A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences.
Funding
This work was supported by the Russian Foundation for Basic Research (project code no. 17-03-00197A). This work was supported by the Ministry of Education and Science (AAAA-A19-119011790097-9).
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Gerasimov, V.K., Chalykh, A.E. & Vishnevskii, A.S. Study of Fractal Characteristics of Individual Macromolecular Tangles. Prot Met Phys Chem Surf 56, 510–513 (2020). https://doi.org/10.1134/S2070205120030156
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S2070205120030156