Skip to main content
SpringerLink
Log in

Hydrolysis of Cellulose in the Presence of Catalysts Based on Cesium Salts of Heteropoly Acids

  • BIOCATALYSIS
  • Published:
Catalysis in Industry Aims and scope Submit manuscript

Abstract

The paper presents the results of studies of catalytic properties of cesium salts of heteropoly acids Cs4–хHхSiW12O40 (x = 3 and 3.5), Cs3–хHхPMo12O40 and Cs3–хHхPW12O40 (x = 2 and 2.5) for hydrolysis of cellulose to glucose at 180°C under argon atmosphere. Glucose is shown to be the main reaction product. The maximum hourly yield equal to 23% is observed in the presence of Cs3HSiW12O40. It is assumed that the catalyst efficiency is affected by the specific surface area. It is established that both heterogeneous and homogeneous processes occur in the presence of the salts due to leaching of the active component to the solution. The prepared salts are demonstrated to be more efficient than systems reported previously in literature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. Besson, M., Gallezot, P., and Pinel, C., Chem. Rev., 2014, vol. 114, no. 3, pp. 1827–1870. https://doi.org/10.1021/cr4002269

    Article  CAS  PubMed  Google Scholar 

  2. Kuznetsov, B.N., Sorosov. Obraz. Zh., 1996, no. 12, pp. 47–55.

  3. Gallezot, P., Chem. Soc. Rev., 2012, vol. 41, no. 4, pp. 1538–1558. https://doi.org/10.1039/C1CS15147A

    Article  CAS  PubMed  Google Scholar 

  4. Mukherjee, A., Dumont, M.-J., and Raghavan, V., Biomass Bioenergy, 2015, vol. 72, pp. 143–183. https://doi.org/10.1016/j.biombioe.2014.11.007

    Article  CAS  Google Scholar 

  5. Bobleter, O., in Polysaccharides. Structural Diversity and Functional Versatility, Severian, D., Ed., New York: Marcel Dekker, 2005, pp. 893–913.

    Google Scholar 

  6. Gromov, N.V., Taran, O.P., and Parmon, V.N., RSC Green Chem. Ser., 2018, vol. 56, pp. 65–97. https://doi.org/10.1039/9781788013567-00065

    Article  CAS  Google Scholar 

  7. Izumi, Y., Ono, M., Kitagawa, M., Yoshida, M., and Urabe, K., Microporous Mater., 1995, vol. 5, no. 4, pp. 255–262. https://doi.org/10.1016/0927-6513(95)00059-3

    Article  CAS  Google Scholar 

  8. Hill, C.L. and Prosser-McCartha, C.M., Coord. Chem. Rev., 1995, vol. 143, pp. 407–455. https://doi.org/10.1016/0010-8545(95)01141-B

    Article  CAS  Google Scholar 

  9. Tian, J., Fang, C., Cheng, M., and Wang, X., Chem. Eng. Technol., 201, vol. 34, no. 3, pp. 482–486. https://doi.org/10.1002/ceat.201000409

  10. Ogasawara, Y., Itagaki, S., Yamaguchi, K., and Mizuno, N., ChemSusChem, 2011, vol. 4, no. 4, pp. 519–525. https://doi.org/10.1002/cssc.201100025

    Article  CAS  PubMed  Google Scholar 

  11. Macht, J., Janik, M.J., Neurock, M., and Iglesia, E., Angew. Chem., Int. Ed., 2007, vol. 46, no. 41, pp. 7864–7868. https://doi.org/10.1002/anie.200701292

    Article  CAS  Google Scholar 

  12. Shimizu, K.-I., Furukawa, H., Kobayashi, N., Itaya, Y., and Satsuma, A., Green Chem., 2009, vol. 11, no. 10, pp. 1627–1632. https://doi.org/10.1039/B913737H

    Article  CAS  Google Scholar 

  13. Tian, J., Wang, J., Zhao, S., Jiang, C., Zhang, X., and Wang, X., Cellulose, 2010, vol. 17, no. 3, pp. 587–594. https://doi.org/10.1007/s10570-009-9391-0

    Article  CAS  Google Scholar 

  14. Okuhara, T., Watanabe, H., Nishimura, T., Inumaru, K., and Misono, M., Chem. Mater., 2000, vol. 12, no. 8, pp. 2230–2238. https://doi.org/10.1021/cm9907561

    Article  CAS  Google Scholar 

  15. Gromov, N.V., Taran, O.P., Semeykina, V.S., Danilova, I.G., Pestunov, A.V., Parkhomchuk, E.V., and Parmon, V.N., Catal. Lett., 2017, vol. 147, no. 6, pp. 1485–1495. https://doi.org/10.1007/s10562-017-2056-y

    Article  CAS  Google Scholar 

  16. Kozhevnikov, I.V. Catalysis by Polyoxometalates, Liverpool: Wiley, 2002.

    Google Scholar 

  17. Gromov, N.V., Medvedeva, T.B., Taran, O.P., Timofeeva, M.N., Said-Aizpuru, O., Panchenko, V.N., Gerasimov, E. Yu., Kozhevnikov I.V., and Parmon V.N., Appl. Catal., A, 2020, vol. 595, p. 117489. https://doi.org/10.1016/j.apcata.2020.117489

  18. Geboers, J., Van de Vyver, S., Carpentier, K., Jacobs, P., and Sels, B., Green Chem., 2011, vol. 13, no. 8, pp. 2167–2174. https://doi.org/10.1039/C1GC15350A

    Article  CAS  Google Scholar 

  19. Grosh, A.K. and Moffat, J.B., J. Catal., 1986, vol. 101, no. 2, pp. 238–245. https://doi.org/10.1016/0021-9517(86)90249-6

    Article  Google Scholar 

  20. Tarabanko, N., Tarabanko, V.E., Kukhtetskiy, S.V., and Taran, O.P., ChemPhysChem, 2019, vol. 20, no. 5, pp. 706–718. https://doi.org/10.1002/cphc.201801160

    Article  CAS  PubMed  Google Scholar 

  21. Gromov, N.V., Medvedeva, T.B., Taran, O.P., Bukhtiyarov, A.V., Aymonier, C., Prosvirin, I.P., and Parmon, V.N., Top. Catal., 2018, vol. 61, nos. 18–19, pp. 1912–1927. https://doi.org/10.1007/s11244-018-1049-4

  22. Cheng, M., Shi, T., Guan, H., Wang, S., Wang, X., and Jiang, Z., Appl. Catal., B, 2011, vol. 107, nos. 1–2, pp. 104–109. https://doi.org/10.1016/j.apcatb.2011.07.002

Download references

Funding

The work was fulfilled with financial support from the Russian Foundation for Basic Research (project 18-33-01007).

Author information

Authors and Affiliations

  1. Boreskov Institute of Catalysis (BIC), Novosibirsk, Russia

    N. V. Gromov, T. B. Medvedeva, O. P. Taran, M. N. Timofeeva & V. N. Parmon

  2. Novosibirsk State Technical University (NSTU), Novosibirsk, Russia

    N. V. Gromov & M. N. Timofeeva

  3. Institute of Chemistry and Chemical Technology (ICCT), Krasnoyarsk Research Center, Russia

    O. P. Taran

Authors
  1. N. V. Gromov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. B. Medvedeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. P. Taran
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. N. Timofeeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. N. Parmon
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to N. V. Gromov, T. B. Medvedeva, O. P. Taran, M. N. Timofeeva or V. N. Parmon.

Ethics declarations

This paper was translated by the authors.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gromov, N.V., Medvedeva, T.B., Taran, O.P. et al. Hydrolysis of Cellulose in the Presence of Catalysts Based on Cesium Salts of Heteropoly Acids. Catal. Ind. 13, 73–80 (2021). https://doi.org/10.1134/S2070050421010049

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070050421010049

Keywords:

Search

Navigation