Skip to main content
SpringerLink
Log in

Catalysts based on ferrierite for the selective hydrocracking of n-hexane

  • Catalysis in Chemical and Petrochemical Industry
  • Published:
Catalysis in Industry Aims and scope Submit manuscript

Abstract

Supported platinum catalysts based on ferrierite type zeolite with Pt content in the range of 1.3–2.8 wt % are prepared. The localization of Pt in zeolite channels is studied for the first time. It is shown that the platinum localized in them increases the yield of products from the selective hydrocracking of n-hexane. Platinum on the outer surface of the zeolite crystals participates in the transformation of n-hexane in the direction of forming hydrocarbons with isomeric structure. The catalysts can be used to improve the octane rating of reformed gasoline, owing to the selective removal of low-octane n-paraffin hydrocarbons and the increase of the portion of high-octane isoparaffin hydrocarbons in the catalytic reforming gasolines.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Russian Federation Government’s Decree, no. 118, On Approval of Technical Regulations On Requirements to Automobile and Aviation Gasoline, Diesel, and Ship Fuel, Fuel for Jet Engines and Furnace Oil, February 27, 2008.

  2. Maesen, T.L.M. and Beerdsen, E., J. Catal., 2006, vol. 273, p. 278.

    Article  Google Scholar 

  3. Chen, N.G., Oil & Gas J., 1968, no. 47, p. 154.

  4. US Patent 3379640, US Patent 3844934, US Patent 3849290.

  5. Georgievskii, V.Yu., Maslyanskii, G.N., and Rozenblit, A.B., Khim. Tekhnol. Topl. Masel, 1979, no. 10, p. 14.

  6. Brovko, V.N., Bursian N.R., Varshavskii, O.M., Khim. Tekhnol. Topl. Masel, 1991, no. 11, p. 2.

  7. Meier, W.M. and Olson, D.H., Atlas of Zeolite Structure Types, London: Butterworths, 1987.

    Google Scholar 

  8. Gregg, S.J. and Sing, K.S.W., Adsorption, Surface Area and Porosity, New York: Academic Press, 1982.

    Google Scholar 

  9. Rouquerol, J., Avnir, D., Everett, D.H., et al., Pure Appl. Chem., 1994, vol. 66, no. 8, p. 1739.

    Article  CAS  Google Scholar 

  10. Dubinin, M.M., Adsorbtsiya i poristost’ (Adsorption and Porosity), Moscow: VAKhZ, 1972.

    Google Scholar 

  11. Belyi, A.S., Smolikov, M.D., Fenelonov, V.B., Gavrilov, V.Yu., and Duplyakin, V.K., Kinet. Katal., 1986, vol. 27, no. 3, p. 703.

    CAS  Google Scholar 

  12. Belyi, A.S., Smolikov, M.D., Fenelonov, V.B., Gavrilov, V.Yu., and Duplyakin, V.K., Kinet. Katal., 1986, vol. 27, no. 6, p. 1414.

    CAS  Google Scholar 

  13. Drozdov, V.A., Doronin, V.P., Sorokina, T.P., Smolikov, M.D., Kireeva, T.V., Abstracts of Papers (Part I), Rossiisko-Koreiskii Seminar po katalizu (Russian-Korean Seminar on Catalysis), Novosibirsk, 1995, p. 67.

  14. Grinberg, A.A., Vvedenie v khimiyu koordinatsionnykh soedinenii (Introduction to the Chemistry of Coordination Compounds), Moscow: Khimiya, 1966.

    Google Scholar 

  15. Zhdanov, S.P., Khvoshchev, S.S., and Samulevich, N.N., Sinteticheskie tseolity (Synthetic Zeolites), Moscow: Khimiya, 1981.

    Google Scholar 

  16. Break, D.W., Zeolite Molecular Sieves, New York: Wiley, 1973.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Hydrocarbon Processing Problems, Siberian Branch, Russian Academy of Sciences, Omsk, 644040, Russia

    M. D. Smolikov, N. I. Goryanskaya, E. V. Zatolokina, D. I. Kiryanov, L. I. Bikmetova, V. P. Doronin, V. A. Drozdov & A. S. Belyi

  2. Omsk State Technical University, Omsk, 644050, Russia

    M. D. Smolikov, V. A. Drozdov & A. S. Belyi

Authors
  1. M. D. Smolikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. I. Goryanskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. V. Zatolokina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. D. I. Kiryanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. L. I. Bikmetova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. P. Doronin
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. V. A. Drozdov
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. A. S. Belyi
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © M.D. Smolikov, N.I. Goryanskaya, E.V. Zatolokina, D.I. Kiryanov, L.I. Bikmetova, V.P. Doronin, V.A. Drozdov, A.S. Belyi, 2012, published in Kataliz v Promyshlennosti.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Smolikov, M.D., Goryanskaya, N.I., Zatolokina, E.V. et al. Catalysts based on ferrierite for the selective hydrocracking of n-hexane. Catal. Ind. 4, 162–167 (2012). https://doi.org/10.1134/S2070050412030105

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070050412030105

Keywords

Search

Navigation