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Determination of constants of the reaction of epoxy model compounds with organic amines in actual conditions

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Abstract

Kinetic studies of the interaction of monoepoxides with primary and secondary monoamines are carried out. It is shown that the reactivity of the epoxide ring of an active modifier depends on the structure during interaction both in bulk and in solvent environment. It was found that the ratio of the constants of the reaction of primary amino groups with an epoxy ring to the constants of the secondary amine is about 2.

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Authors and Affiliations

  1. Kazan State Technological University, ul. Karla Marksa 68, Kazan, Tatarstan, 420015, Russia

    R. M. Garipov & A. A. Efremova

  2. Danaflex CJSC, ul. Rodina 7, Kazan, Tatarstan, 420087, Russia

    L. R. Garipova

Authors
  1. R. M. Garipov
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  2. L. R. Garipova
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  3. A. A. Efremova
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Correspondence to R. M. Garipov.

Additional information

Original Russian Text © R.M. Garipov, L.R. Garipova, A.A. Efremova, 2012, published in Klei. Germetiki. Tekhnologii, 2012, No. 1, pp. 27–31.

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Garipov, R.M., Garipova, L.R. & Efremova, A.A. Determination of constants of the reaction of epoxy model compounds with organic amines in actual conditions. Polym. Sci. Ser. D 5, 185–189 (2012). https://doi.org/10.1134/S1995421212030070

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  • DOI: https://doi.org/10.1134/S1995421212030070

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