Abstract
The process of fabrication of plasmon mesostructures based on opal-like films (films consisting of silica spheres of similar diameters) and homogeneous and quasi-homogeneous sol-gel SiO2 films has been elaborated. The kinetics of formation of silver nanoparticles (NPs) in such films in the course of thermal treatment has been studied. Two mechanisms of the formation of the plasmon absorption bands in such structures have been revealed. The results of the plasmon amplification of the Raman scattering signal of the Rhodamine 6G dye on opal-like films containing silver NPs have been reported.
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L. A. Golovan’, V. Yu. Timoshenko, and P. K. Kashkarov, “Optical Properties of Porous-System-Based Nanocomposites,” Phys. Usp. 50, 595 (2007).
S. Lal, S. Link, and N. J. Halas, “Nano-Optics from Sensing to Waveguiding,” Nature Photon. 1, 641–648 (2007).
J. A. Schuller, E. S. Barnard, W. Cai, Y. C. Jun, J. S. White, and M. L. Brongersma, “Plasmonics for Extreme Light Concentration and Manipulation,” Nature Mater. 9, 193–204 (2010).
V. V. Klimov, Nanoplasmonics (Fizmatlit, Moscow, 2010) [inRussian].
M. Moskovits, “Surface-Enhanced Spectroscopy,” Rev. Mod. Phys. 57, 783–826 (1985).
K. Aslan, Z. Leonenko, J. R. Lakowicz, and C. D. Geddes, “Annealed Silver-Island Films for Applications in Metal-Enhanced Fluorescence: Interpretation in Terms of Radiating Plasmons,” J. Fluoresc. 15, 643–654 (2005).
P. Chakraborty, “Metal Nanoclusters in Glasses as Non-Linear Photonic Materials,” J. Mater. Sci. 33, 2235–2249 (1998).
C. López, “Materials Aspects of Photonic Crystals,” Adv. Mater. 15, 1679–1704 (2003).
P. D. García, R. Sapienza, and C. López, “Photonic Glasses: A Step Beyond White Paint,” Adv. Mater. 21, 18 (2009).
Nanomaterials. III. Photonic Crystals and Nanocomposites Based on Opal Matrixes, Collective Monography, Ed. by M. I. Samoilovich (Tekhnomash, Moscow, 2007) [in Russian].
W. Stöber, A. Fink, and E. Bohn, “Controlled Growth of Monodisperse Silica Spheres in the Micron Size Range,” J. Colloid Interface Sci. 26, 62–69 (1968).
A. O. Rybaltovskii, Yu. S. Zavorotnyi, N. V. Minaev, M. I. Samoilovich, P. S. Timashev, M. Yu. Tsvetkov, and V. N. Bagratashvili, “Synthesis of Silver Nanocomposites by SCF Impregnation of Matrices of Synthetic Opal and Vycor Glass by the Ag(hfac)COD Precursor,” Sverkhkrit. Flyuidy: Teor. Prakt. 4(2), 3–14 (2009).
G. De, B. Karmakar, and D. Ganguli, “Hydrolysis-Condensation Reactions of TEOS in the Presence of Acetic Acid Leading to the Generation of Glass-Like Silica Microspheres in Solution at Room Temperature,” J. Mater. Chem. 10, 2289–2293 (2000).
B. Karmakar, G. De, D. Kundu, and D. Ganguli, “Silica Microspheres from the System Tetraethyl Orthosilicate-Acetic Acid-Water,” J. Non-Cryst. Sol. 135, 29–36 (1991).
M. Yu. Tsvetkov, Extended Abstract of Candidate’s Dissertation (IPLIT RAN, Shatura, 2008).
B. Akkopru and C. Durucan, “Preparation and Microstructure of Sol-Gel Derived Silver-Doped Silica,” J. Sol-Gel Sci. Technol. 43, 227–236 (2007).
U. Kreibig and M. Vollmer, Optical Properties of Metal Clusters (Springer-Verlag, New York, 1995).
Yu. A. Krutyakov, A. A. Kudrinski, A. Yu. Olenin, and G. V. Lisichkin, “Synthesis and Properties of Silver Nanoparticles: Results and Prospects,” Usp. Khim. 77, 242–269 (2008).
U. Kreibig, M. Gartz, A. Hilger, H. Hövel, M. Quinten, D. Wagner, “A Short Survey of Optical Properties of Metal Nanostructures,” in Functional Properties of Nanostructured Materials, Ed. by R. Kassing et al. (Springer, 2005).
R. S. Berry and B. M. Smirnov, “Phase Transitions in Various Kinds of Clusters,” Phys. Usp. 52, 137 (2009).
S. H. Yoon, J. H. Lee, P. C. Lee, J. D. Nam, H.-C. Jung, Y. S. Oh, T. S. Kim, and Y. K. Lee, “Sintering and Consolidation of Silver Nanoparticles Printed on Polyimide Substrate Films,” Macromol. Res. 17, 568–574 (2009).
A. V. Gur’yanov, M. I. Samoilovich, M. Yu. Tsvetkov, E. B. Intyushin, and Yu. I. Chigirinskii, “Characteristic Features of Photoluminescence of the Opal — Tellurite Glass - Er3+ Nanocomposite,” Zh. Prikl. Spektrosk. 70, 285–287 (2003).
M. A. Garcia, M. Garcia-Heras, E. Cano, J. M. Bastidas, M. A. Villegas, E. Montero, J. Llopis, C. Sada, G. De Marchi, G. Battaglin, and P. Mazzoldi, “Photoluminescence of Silver in Glassy Matrices,” J. Appl. Phys. 96, 3737–3741 (2004).
S. Chan, S. Kwon, T.-W. Koo, L. P. Lee, and A. A. Berlin, “Surface-Enhanced Raman Scattering of Small Molecules from Silver-Coated Silicon Nanopores,” Adv. Mater. 15, 1595–1598 (2003).
T. Hassel, L. Lagonigro, A. C. Peacock, S. Yoda, P. D. Brown, P. J. A. Sazio, and S. M. Howdle, “Silver Nanoparticle Impregnated Polycarbonate Substrates for Surface Enhanced Raman Spectroscopy,” Adv. Func. Mater. 18, 1265–1271 (2008).
J. N. Anker, W. P. Hall, O. Lyandres, N. C. Shan, J. Zhao, and R. P. Van Duyne, “Biosensing with Plasmonic Nanosensors,” Nature Mater. 7, 442–453 (2008).
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Original Russian Text © M.Yu. Tsvetkov, V.N. Bagratashvili, V.Ya. Panchenko, A.O. Rybaltovskii, M.I. Samoilovich, M.A. Timofeev, 2011, published in Rossiiskie Nanotekhnologii, 2011, Vol. 6, Nos. 9–10.
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Tsvetkov, M.Y., Bagratashvili, V.N., Panchenko, V.Y. et al. Plasmon resonances of silver nanoparticles in silica based meso-structured films. Nanotechnol Russia 6, 619 (2011). https://doi.org/10.1134/S1995078011050156
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DOI: https://doi.org/10.1134/S1995078011050156